Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)


organic compounds



sj5378 scheme

Acta Cryst. (2014). E70, o59-o60    [ doi:10.1107/S1600536813033424 ]

N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine

Z.-Y. Li, P. Wang and X. Chen

Abstract: The title mol­ecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-tri­methyl­silyfluorenyl lithium and 2-meth­oxy­benzo­nitrile. The fluorene ring system is substanti­ally planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-meth­oxy­benzyl­amine ring plane. In the crystal, mol­ecules are linked by N-H...[pi] and C-H...[pi] inter­actions, which leads to the formation of two-dimensional network lying parallel to the bc plane.


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