Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 1 (January 2014)

metal-organic compounds

tk5276 scheme

Acta Cryst. (2014). E70, m14-m15    [ doi:10.1107/S1600536813032480 ]

Tri-[mu]-chlorido-bis­[([eta]5-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation

L. Ezzedinloo, S. Shrestha, M. Bhadbhade and S. Colbran

Abstract: In the title complex salt, [{([eta]5-C5Me5)Rh}2([mu]-Cl)3]PF6, the dinuclear, single-charged cation is formed by the cojoining of two classic ([eta]5-C5Me5)RhCl3 `piano-stool' units by bridging of the three choride ligand `legs'. The crystal structure shows several close H...F contacts between the hexa­fluorido­phosphate counter-ions and the C5Me5 ligands.

CCDC reference: 974403

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