metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

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ISSN: 2056-9890

Bis(μ-nitrato-κ2O:O)bis­­{[1,2-bis­­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ2P,P′]silver(I)} di­chloro­methane disolvate

aDepartment of Chemistry, University of Science and Technology Beijing, Beijing 100083, People's Republic of China
*Correspondence e-mail: yangliguo116@163.com

(Received 16 March 2014; accepted 19 March 2014; online 22 March 2014)

The title compound, [Ag2(NO3)2(C14H38B10P2)2]·2CH2Cl2, was synthesized by the reaction of 1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane with AgNO3. The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diiso­propyl­phosphanyl-closo-carborane ligand is coordin­ated in a bidentate manner to the AgI atom through the two P atoms. The distorted tetra­hedral coordination of the metal is completed by two O atoms of two bridging nitrate anions. The separation between the two AgI atoms is 3.8913 (5) Å. C—H⋯O hydrogen bonds are observed involving the dichloromethane solvent molecule and the nitrate anion.

Related literature

For related structures, see: Zhang et al. (2006[Zhang, D.-P., Dou, J.-M., Li, D.-C. & Wang, D.-Q. (2006). Acta Cryst. E62, o418-o419.]); Paavola et al. (2002[Paavola, S., Kivekäs, R., Teixidor, F. & Viñas, C. (2002). J. Organomet. Chem. 606, 183-187.], 2002a[Paavola, S., Teixidor, F., Viñas, C. & Kivekäs, R. (2002a). Acta Cryst. C58, m237-m239.],b[Paavola, S., Teixidor, F., Viñas, C. & Kivekäs, R. (2002b). J. Organomet. Chem. 645, 39-46.]). For the synthesis and structure of 1,2-bis­(di­iso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane, see: Kivekäs et al. (1995[Kivekäs, R., Sillanpää, R., Teixidor, F., Viñas, C., Nuñez, R. & Abad, M. (1995). Acta Cryst. C51, 1864-1868.]).

[Scheme 1]

Experimental

Crystal data
  • [Ag2(NO3)2(C14H38B10P2)2]·2CH2Cl2

  • Mr = 1262.58

  • Monoclinic, P 21 /n

  • a = 13.9256 (15) Å

  • b = 10.3003 (10) Å

  • c = 21.8075 (19) Å

  • β = 107.734 (2)°

  • V = 2979.4 (5) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 0.98 mm−1

  • T = 298 K

  • 0.43 × 0.36 × 0.31 mm

Data collection
  • Bruker SMART1000 CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.677, Tmax = 0.751

  • 14624 measured reflections

  • 5264 independent reflections

  • 3849 reflections with I > 2σ(I)

  • Rint = 0.027

Refinement
  • R[F2 > 2σ(F2)] = 0.034

  • wR(F2) = 0.091

  • S = 1.05

  • 5264 reflections

  • 315 parameters

  • 6 restraints

  • H-atom parameters constrained

  • Δρmax = 0.37 e Å−3

  • Δρmin = −0.41 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
C15—H15A⋯O3i 0.97 2.48 3.203 (6) 132
C15—H15A⋯O1i 0.97 2.48 3.389 (8) 155
Symmetry code: (i) -x+1, -y, -z.

Data collection: SMART (Siemens, 1996[Siemens (1996). SMART and SAINT. Siemens Analytical X-Ray Instruments Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Siemens, 1996[Siemens (1996). SMART and SAINT. Siemens Analytical X-Ray Instruments Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supporting information


Comment top

The synthesis and structure of 1,2-(PiPr2)2-1,2-C2B10H10 was reported by Kivekäs et al. (1995). Since then, only a few complexes of this ligand with Pt(II) and Pd(II) have been described (Paavola, Kivekäs et al., 2002; Paavola et al., 2002a,b). Here we report the structure of this ligand combined with Ag and nitrate anions.

As shown in Fig. 1, the coordination of the Ag atom is distorted tetrahedral, formed by two O atom from two NO3 anions and the P atoms of the diisopropylphosphanyl-closo-carborane ligand. The two P—Ag bond lengths are slightly shorter than the corresponding bond lengths in the complex [Ag2Cl2(C26H30B10P2)2].2CH2Cl2 (2.5052 (14) Å; Zhang et al., 2006). The P—Ag—P angle is slightly larger than the corresponding value of 89.80 (5) Å for the complex [Ag2Cl2(C26H30B10P2)2].2CH2Cl2 (Zhang et al., 2006). The five-memebered chelate ring formed by the silver atom, two phosphorus atoms and two carbon atoms of the carborane skeleton is strongly flattened with a maximum deviation of 0.088 (3) Å for atom C2. The torsion angle P1—C1—C2—P2 is -2.7 (3)°, viz. smaller than that of 12.1 (2)° in the free ligand (Kivekäs et al., 1995). In the crystal, intermolecular C—H···O hydrogen bonds involving the nitrate anion and the dichloromethane solvent molecule are observed (Table 1).

Related literature top

For related structures, see: Zhang et al. (2006); Paavola et al. (2002, 2002a,b). For the synthesis and structure of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane, see: Kivekäs et al. (1995).

Experimental top

The title compound was synthesizd by the reaction of 1 mmol AgNO3 and 1 mmol 1,2-(PiPr2)2-1,2-C2B10H10 in 10 ml dichloromethane under the protection of N2, refluxed for 4 h, then a colourless solution formed, and crystals suitable for X-ray diffraction were obtained from a dichloromethane- n-hexane (1:3 v/v solution (yield 60.7%, m.p. 553–555 K). FTIR (KBr) v (cm-1): 2989, 2966, 2930, 2872 (C—H); 2614, 2602, 2585, 2556 (B—H); 1071 (C—P).

Refinement top

All H atoms were placed geometrically and treated as riding on their parent atoms, with B—H 1.10, C—H 0.96 (methyl), C—H 0.98 Å (isopropyl), with Uiso(H) = 1.2Ueq(B, C) or 1.5Ueq(C) for methyl H atoms. A rigid bond restraints were applied to the Uij values of atoms Ag1, P1 and P2 via DELU instruction of SHELXL-97 (Sheldrick, 2008).

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title compound with 30% probability displacement ellipsoids for non-H atoms. H atoms are omitted for clarity. Symmetry code: (A) -x + 1,-y,-z.
Bis(µ-nitrato-κ2O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ2P,P']silver(I)} dichloromethane disolvate top
Crystal data top
[Ag2(NO3)2(C14H38B10P2)2]·2CH2Cl2F(000) = 1288
Mr = 1262.58Dx = 1.407 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 5416 reflections
a = 13.9256 (15) Åθ = 2.5–26.4°
b = 10.3003 (10) ŵ = 0.98 mm1
c = 21.8075 (19) ÅT = 298 K
β = 107.734 (2)°Block, yellow
V = 2979.4 (5) Å30.43 × 0.36 × 0.31 mm
Z = 2
Data collection top
Bruker SMART1000 CCD
diffractometer
5264 independent reflections
Radiation source: fine-focus sealed tube3849 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.027
phi and ω scansθmax = 25.0°, θmin = 1.6°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1316
Tmin = 0.677, Tmax = 0.751k = 1211
14624 measured reflectionsl = 2525
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.034Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.091H-atom parameters constrained
S = 1.05 w = 1/[σ2(Fo2) + (0.0346P)2 + 2.5405P]
where P = (Fo2 + 2Fc2)/3
5264 reflections(Δ/σ)max = 0.001
315 parametersΔρmax = 0.37 e Å3
6 restraintsΔρmin = 0.41 e Å3
Crystal data top
[Ag2(NO3)2(C14H38B10P2)2]·2CH2Cl2V = 2979.4 (5) Å3
Mr = 1262.58Z = 2
Monoclinic, P21/nMo Kα radiation
a = 13.9256 (15) ŵ = 0.98 mm1
b = 10.3003 (10) ÅT = 298 K
c = 21.8075 (19) Å0.43 × 0.36 × 0.31 mm
β = 107.734 (2)°
Data collection top
Bruker SMART1000 CCD
diffractometer
5264 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
3849 reflections with I > 2σ(I)
Tmin = 0.677, Tmax = 0.751Rint = 0.027
14624 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0346 restraints
wR(F2) = 0.091H-atom parameters constrained
S = 1.05Δρmax = 0.37 e Å3
5264 reflectionsΔρmin = 0.41 e Å3
315 parameters
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.64127 (2)0.05086 (3)0.027639 (15)0.05747 (12)
P10.78280 (7)0.00794 (9)0.12339 (4)0.0422 (2)
P20.72744 (7)0.21677 (9)0.01656 (4)0.0446 (2)
C10.8795 (2)0.1294 (3)0.11955 (16)0.0440 (8)
C90.7616 (3)0.0450 (4)0.20219 (18)0.0593 (10)
H90.77040.13900.20840.071*
B10.9356 (3)0.1167 (4)0.05903 (19)0.0444 (10)
H10.92010.03260.02640.053*
N10.5539 (3)0.1960 (3)0.05564 (16)0.0570 (8)
C20.8493 (2)0.2413 (3)0.04724 (16)0.0416 (8)
C100.8432 (3)0.1537 (4)0.13410 (18)0.0573 (10)
H100.89900.15410.17440.069*
B21.0566 (3)0.1903 (6)0.0910 (2)0.0707 (15)
H21.12360.15440.07960.085*
C30.7665 (3)0.1644 (4)0.08742 (17)0.0561 (10)
H30.83000.11700.06990.067*
B30.9592 (3)0.2734 (5)0.0328 (2)0.0561 (11)
H3A0.96410.29130.01590.067*
C110.8355 (4)0.0186 (5)0.26173 (19)0.0807 (14)
H11A0.82630.01830.30000.121*
H11B0.90340.00350.26150.121*
H11C0.82300.11030.26090.121*
C40.6685 (3)0.3796 (4)0.0364 (2)0.0689 (12)
H40.71330.43540.05180.083*
C50.6447 (4)0.4463 (5)0.0192 (3)0.0957 (18)
H5A0.60850.52520.00420.143*
H5B0.70640.46590.05220.143*
H5C0.60420.38990.03620.143*
B40.9034 (4)0.3850 (5)0.0729 (2)0.0642 (13)
H4A0.87100.47770.05110.077*
B51.0043 (3)0.1015 (6)0.1427 (2)0.0632 (13)
H51.03750.00910.16440.076*
C120.7628 (4)0.2512 (4)0.1399 (2)0.0877 (15)
H12A0.70690.25000.10110.132*
H12B0.73990.22780.17570.132*
H12C0.79140.33680.14660.132*
B60.8485 (4)0.2899 (4)0.1227 (2)0.0564 (12)
H60.77720.31700.13110.068*
B70.9491 (4)0.2154 (5)0.1833 (2)0.0691 (14)
H70.94610.19960.23260.083*
B81.0358 (4)0.3580 (6)0.1012 (3)0.0831 (18)
H81.09010.43270.09730.100*
B90.9660 (5)0.3716 (6)0.1566 (3)0.0857 (18)
H9A0.97300.45610.18850.103*
C60.6908 (4)0.0662 (5)0.1280 (2)0.0913 (16)
H6A0.62760.10870.14770.137*
H6B0.68120.00280.10080.137*
H6C0.71620.03120.16080.137*
C70.7878 (4)0.2708 (5)0.1299 (2)0.0828 (14)
H7A0.81790.23340.16000.124*
H7B0.83310.33330.10360.124*
H7C0.72580.31280.15300.124*
B101.0634 (4)0.2546 (7)0.1678 (3)0.0881 (19)
H10A1.13530.26240.20670.106*
C130.6523 (4)0.0158 (6)0.1985 (2)0.0881 (15)
H13A0.64030.07590.19320.132*
H13B0.60770.06110.16250.132*
H13C0.64030.04400.23750.132*
C80.5700 (4)0.3571 (6)0.0918 (3)0.111 (2)
H8A0.52540.30320.07690.166*
H8B0.58530.31500.12700.166*
H8C0.53810.43900.10600.166*
C140.8825 (4)0.1983 (4)0.0795 (2)0.0742 (13)
H14A0.89870.28910.08450.111*
H14B0.94190.14980.08070.111*
H14C0.83170.18410.03900.111*
Cl10.32691 (14)0.43727 (14)0.21349 (8)0.1137 (5)
Cl20.42679 (13)0.19019 (16)0.24175 (8)0.1185 (5)
O20.52475 (19)0.0987 (3)0.03220 (15)0.0713 (8)
O30.6446 (2)0.2156 (3)0.04215 (16)0.0875 (10)
O10.4915 (3)0.2662 (3)0.09218 (17)0.0919 (11)
C150.3518 (5)0.2913 (6)0.1839 (2)0.1077 (19)
H15A0.38480.30720.15130.129*
H15B0.28850.24760.16320.129*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.03991 (16)0.0667 (2)0.0621 (2)0.01337 (14)0.01007 (13)0.00590 (16)
P10.0444 (5)0.0431 (5)0.0413 (5)0.0005 (4)0.0163 (4)0.0016 (4)
P20.0398 (5)0.0418 (5)0.0504 (5)0.0021 (4)0.0111 (4)0.0074 (4)
C10.0428 (19)0.048 (2)0.0401 (18)0.0014 (16)0.0118 (15)0.0069 (16)
C90.067 (3)0.068 (3)0.051 (2)0.003 (2)0.031 (2)0.001 (2)
B10.034 (2)0.052 (3)0.048 (2)0.0008 (18)0.0145 (18)0.002 (2)
N10.058 (2)0.054 (2)0.064 (2)0.0071 (18)0.0267 (18)0.0053 (18)
C20.0419 (19)0.0362 (19)0.050 (2)0.0049 (15)0.0188 (16)0.0041 (16)
C100.074 (3)0.044 (2)0.054 (2)0.010 (2)0.019 (2)0.0049 (18)
B20.039 (2)0.097 (4)0.072 (3)0.014 (3)0.011 (2)0.004 (3)
C30.062 (2)0.061 (3)0.044 (2)0.005 (2)0.0133 (18)0.0022 (18)
B30.048 (3)0.059 (3)0.066 (3)0.015 (2)0.025 (2)0.002 (2)
C110.101 (4)0.100 (4)0.043 (2)0.009 (3)0.024 (2)0.005 (2)
C40.059 (3)0.056 (3)0.094 (3)0.017 (2)0.027 (2)0.022 (2)
C50.091 (4)0.064 (3)0.150 (5)0.035 (3)0.062 (4)0.021 (3)
B40.075 (3)0.043 (3)0.082 (3)0.022 (2)0.034 (3)0.013 (2)
B50.039 (2)0.086 (4)0.054 (3)0.002 (2)0.001 (2)0.001 (3)
C120.130 (5)0.050 (3)0.095 (4)0.010 (3)0.052 (3)0.010 (3)
B60.072 (3)0.047 (3)0.056 (3)0.009 (2)0.028 (2)0.017 (2)
B70.067 (3)0.088 (4)0.048 (3)0.026 (3)0.010 (2)0.022 (3)
B80.070 (3)0.094 (4)0.083 (4)0.045 (3)0.020 (3)0.019 (3)
B90.102 (5)0.080 (4)0.077 (4)0.045 (4)0.029 (3)0.038 (3)
C60.116 (4)0.088 (4)0.062 (3)0.031 (3)0.015 (3)0.014 (3)
C70.102 (4)0.089 (4)0.063 (3)0.010 (3)0.033 (3)0.014 (3)
B100.062 (3)0.121 (5)0.070 (3)0.040 (3)0.003 (3)0.018 (3)
C130.079 (3)0.123 (4)0.079 (3)0.004 (3)0.049 (3)0.011 (3)
C80.073 (3)0.118 (5)0.124 (5)0.029 (3)0.004 (3)0.047 (4)
C140.097 (4)0.046 (2)0.087 (3)0.015 (2)0.039 (3)0.001 (2)
Cl10.1405 (14)0.0763 (9)0.1027 (10)0.0029 (9)0.0049 (9)0.0015 (8)
Cl20.1154 (12)0.1009 (11)0.1187 (12)0.0243 (9)0.0050 (9)0.0136 (9)
O20.0384 (14)0.0748 (18)0.101 (2)0.0155 (11)0.0213 (11)0.0315 (15)
O30.066 (2)0.099 (3)0.097 (2)0.0177 (18)0.0253 (18)0.013 (2)
O10.093 (2)0.085 (2)0.101 (2)0.035 (2)0.035 (2)0.040 (2)
C150.107 (4)0.136 (5)0.070 (3)0.010 (4)0.014 (3)0.028 (3)
Geometric parameters (Å, º) top
Ag1—O22.328 (3)C4—C81.545 (6)
Ag1—O2i2.395 (3)C4—H40.9800
Ag1—P12.4357 (9)C5—H5A0.9600
Ag1—P22.4482 (10)C5—H5B0.9600
P1—C101.848 (4)C5—H5C0.9600
P1—C11.859 (4)B4—B91.773 (8)
P1—C91.869 (4)B4—B81.779 (8)
P2—C21.855 (3)B4—B61.797 (7)
P2—C41.860 (4)B4—H4A1.1000
P2—C31.867 (4)B5—B71.779 (7)
C1—B51.679 (5)B5—B101.786 (8)
C1—B71.684 (5)B5—H51.1000
C1—B61.716 (6)C12—H12A0.9600
C1—B11.731 (5)C12—H12B0.9600
C1—C21.894 (5)C12—H12C0.9600
C9—C131.530 (6)B6—B71.782 (7)
C9—C111.536 (6)B6—B91.788 (7)
C9—H90.9800B6—H61.1000
B1—C21.722 (5)B7—B91.752 (8)
B1—B31.776 (6)B7—B101.771 (8)
B1—B21.785 (6)B7—H71.1000
B1—B51.791 (6)B8—B101.748 (9)
B1—H11.1000B8—B91.772 (8)
N1—O11.221 (4)B8—H81.1000
N1—O31.223 (4)B9—B101.775 (9)
N1—O21.248 (4)B9—H9A1.1000
C2—B41.678 (5)C6—H6A0.9600
C2—B31.686 (5)C6—H6B0.9600
C2—B61.723 (5)C6—H6C0.9600
C10—C141.525 (5)C7—H7A0.9600
C10—C121.537 (6)C7—H7B0.9600
C10—H100.9800C7—H7C0.9600
B2—B31.771 (7)B10—H10A1.1000
B2—B51.772 (7)C13—H13A0.9600
B2—B81.776 (9)C13—H13B0.9600
B2—B101.777 (8)C13—H13C0.9600
B2—H21.1000C8—H8A0.9600
C3—C71.522 (5)C8—H8B0.9600
C3—C61.532 (6)C8—H8C0.9600
C3—H30.9800C14—H14A0.9600
B3—B41.761 (7)C14—H14B0.9600
B3—B81.776 (7)C14—H14C0.9600
B3—H3A1.1000Cl1—C151.713 (6)
C11—H11A0.9600Cl2—C151.721 (6)
C11—H11B0.9600O2—Ag1i2.395 (3)
C11—H11C0.9600C15—H15A0.9700
C4—C51.514 (6)C15—H15B0.9700
O2—Ag1—O2i69.06 (12)B8—B4—B6106.9 (4)
O2—Ag1—P1127.18 (8)C2—B4—H4A122.6
O2i—Ag1—P1122.75 (8)B3—B4—H4A122.5
O2—Ag1—P2125.65 (8)B9—B4—H4A121.4
O2i—Ag1—P2117.89 (8)B8—B4—H4A122.1
P1—Ag1—P295.65 (3)B6—B4—H4A122.7
C10—P1—C1107.71 (17)C1—B5—B2108.0 (3)
C10—P1—C9105.13 (18)C1—B5—B758.2 (2)
C1—P1—C9102.90 (17)B2—B5—B7107.5 (4)
C10—P1—Ag1119.34 (13)C1—B5—B10106.2 (4)
C1—P1—Ag1104.33 (11)B2—B5—B1059.9 (3)
C9—P1—Ag1115.98 (13)B7—B5—B1059.6 (3)
C2—P2—C4106.85 (18)C1—B5—B159.7 (2)
C2—P2—C3103.26 (16)B2—B5—B160.1 (2)
C4—P2—C3106.71 (19)B7—B5—B1105.8 (3)
C2—P2—Ag1104.24 (11)B10—B5—B1106.8 (4)
C4—P2—Ag1119.11 (14)C1—B5—H5122.6
C3—P2—Ag1115.17 (13)B2—B5—H5121.3
B5—C1—B763.9 (3)B7—B5—H5123.0
B5—C1—B6113.8 (3)B10—B5—H5122.5
B7—C1—B663.2 (3)B1—B5—H5122.5
B5—C1—B163.3 (2)C10—C12—H12A109.5
B7—C1—B1113.0 (3)C10—C12—H12B109.5
B6—C1—B1106.3 (3)H12A—C12—H12B109.5
B5—C1—P1124.6 (3)C10—C12—H12C109.5
B7—C1—P1124.0 (3)H12A—C12—H12C109.5
B6—C1—P1116.9 (3)H12B—C12—H12C109.5
B1—C1—P1119.0 (2)C1—B6—C266.8 (2)
B5—C1—C2107.6 (3)C1—B6—B757.5 (2)
B7—C1—C2107.1 (3)C2—B6—B7110.5 (3)
B6—C1—C256.8 (2)C1—B6—B9105.1 (4)
B1—C1—C256.53 (19)C2—B6—B9105.1 (3)
P1—C1—C2117.8 (2)B7—B6—B958.8 (3)
C13—C9—C11111.1 (4)C1—B6—B4110.0 (3)
C13—C9—P1110.2 (3)C2—B6—B456.9 (2)
C11—C9—P1115.9 (3)B7—B6—B4107.5 (4)
C13—C9—H9106.3B9—B6—B459.3 (3)
C11—C9—H9106.3C1—B6—H6120.2
P1—C9—H9106.3C2—B6—H6120.2
C2—B1—C166.5 (2)B7—B6—H6122.1
C2—B1—B357.6 (2)B9—B6—H6124.8
C1—B1—B3110.3 (3)B4—B6—H6122.4
C2—B1—B2105.9 (3)C1—B7—B9108.1 (4)
C1—B1—B2105.1 (3)C1—B7—B10106.6 (3)
B3—B1—B259.6 (3)B9—B7—B1060.5 (3)
C2—B1—B5110.4 (3)C1—B7—B557.9 (2)
C1—B1—B556.9 (2)B9—B7—B5108.5 (4)
B3—B1—B5108.3 (3)B10—B7—B560.4 (3)
B2—B1—B559.4 (3)C1—B7—B659.3 (2)
C2—B1—H1120.0B9—B7—B660.8 (3)
C1—B1—H1120.6B10—B7—B6108.0 (4)
B3—B1—H1121.7B5—B7—B6106.0 (3)
B2—B1—H1124.3C1—B7—H7123.0
B5—B1—H1122.0B9—B7—H7120.7
O1—N1—O3122.5 (4)B10—B7—H7121.6
O1—N1—O2119.1 (4)B5—B7—H7122.7
O3—N1—O2118.3 (3)B6—B7—H7122.2
B4—C2—B363.1 (3)B10—B8—B960.6 (4)
B4—C2—B1112.7 (3)B10—B8—B3108.9 (4)
B3—C2—B162.8 (2)B9—B8—B3107.3 (3)
B4—C2—B663.8 (3)B10—B8—B260.6 (3)
B3—C2—B6113.1 (3)B9—B8—B2107.9 (4)
B1—C2—B6106.4 (3)B3—B8—B259.8 (3)
B4—C2—P2125.8 (3)B10—B8—B4109.1 (4)
B3—C2—P2124.2 (3)B9—B8—B459.9 (3)
B1—C2—P2116.6 (2)B3—B8—B459.4 (3)
B6—C2—P2119.0 (2)B2—B8—B4107.5 (3)
B4—C2—C1107.2 (3)B10—B8—H8120.5
B3—C2—C1106.9 (3)B9—B8—H8121.9
B1—C2—C157.0 (2)B3—B8—H8122.0
B6—C2—C156.4 (2)B2—B8—H8121.9
P2—C2—C1117.5 (2)B4—B8—H8121.8
C14—C10—C12108.2 (3)B7—B9—B8108.1 (4)
C14—C10—P1115.5 (3)B7—B9—B4109.9 (3)
C12—C10—P1106.5 (3)B8—B9—B460.2 (3)
C14—C10—H10108.8B7—B9—B1060.3 (3)
C12—C10—H10108.8B8—B9—B1059.0 (4)
P1—C10—H10108.8B4—B9—B10108.1 (4)
B3—B2—B5109.4 (3)B7—B9—B660.4 (3)
B3—B2—B860.1 (3)B8—B9—B6107.6 (3)
B5—B2—B8107.9 (4)B4—B9—B660.6 (3)
B3—B2—B10107.8 (4)B10—B9—B6107.6 (4)
B5—B2—B1060.4 (3)B7—B9—H9A120.7
B8—B2—B1058.9 (3)B8—B9—H9A122.3
B3—B2—B159.9 (2)B4—B9—H9A120.7
B5—B2—B160.4 (2)B10—B9—H9A122.3
B8—B2—B1106.9 (4)B6—B9—H9A121.8
B10—B2—B1107.4 (3)C3—C6—H6A109.5
B3—B2—H2121.2C3—C6—H6B109.5
B5—B2—H2120.8H6A—C6—H6B109.5
B8—B2—H2122.5C3—C6—H6C109.5
B10—B2—H2122.3H6A—C6—H6C109.5
B1—B2—H2122.2H6B—C6—H6C109.5
C7—C3—C6110.6 (3)C3—C7—H7A109.5
C7—C3—P2117.1 (3)C3—C7—H7B109.5
C6—C3—P2110.2 (3)H7A—C7—H7B109.5
C7—C3—H3106.1C3—C7—H7C109.5
C6—C3—H3106.1H7A—C7—H7C109.5
P2—C3—H3106.1H7B—C7—H7C109.5
C2—B3—B458.2 (2)B8—B10—B7108.3 (4)
C2—B3—B2108.2 (3)B8—B10—B960.4 (4)
B4—B3—B2108.5 (4)B7—B10—B959.2 (3)
C2—B3—B8106.7 (3)B8—B10—B260.5 (3)
B4—B3—B860.4 (3)B7—B10—B2107.6 (3)
B2—B3—B860.1 (3)B9—B10—B2107.7 (4)
C2—B3—B159.6 (2)B8—B10—B5108.6 (4)
B4—B3—B1106.3 (3)B7—B10—B560.0 (3)
B2—B3—B160.4 (3)B9—B10—B5107.2 (4)
B8—B3—B1107.3 (4)B2—B10—B559.7 (3)
C2—B3—H3A122.7B8—B10—H10A120.9
B4—B3—H3A122.4B7—B10—H10A122.0
B2—B3—H3A120.9B9—B10—H10A122.3
B8—B3—H3A122.0B2—B10—H10A121.9
B1—B3—H3A122.3B5—B10—H10A121.9
C9—C11—H11A109.5C9—C13—H13A109.5
C9—C11—H11B109.5C9—C13—H13B109.5
H11A—C11—H11B109.5H13A—C13—H13B109.5
C9—C11—H11C109.5C9—C13—H13C109.5
H11A—C11—H11C109.5H13A—C13—H13C109.5
H11B—C11—H11C109.5H13B—C13—H13C109.5
C5—C4—C8109.6 (4)C4—C8—H8A109.5
C5—C4—P2114.3 (3)C4—C8—H8B109.5
C8—C4—P2105.7 (3)H8A—C8—H8B109.5
C5—C4—H4109.0C4—C8—H8C109.5
C8—C4—H4109.0H8A—C8—H8C109.5
P2—C4—H4109.0H8B—C8—H8C109.5
C4—C5—H5A109.5C10—C14—H14A109.5
C4—C5—H5B109.5C10—C14—H14B109.5
H5A—C5—H5B109.5H14A—C14—H14B109.5
C4—C5—H5C109.5C10—C14—H14C109.5
H5A—C5—H5C109.5H14A—C14—H14C109.5
H5B—C5—H5C109.5H14B—C14—H14C109.5
C2—B4—B358.6 (2)N1—O2—Ag1120.2 (2)
C2—B4—B9107.7 (4)N1—O2—Ag1i128.4 (2)
B3—B4—B9107.9 (4)Ag1—O2—Ag1i110.94 (12)
C2—B4—B8106.9 (4)Cl1—C15—Cl2113.7 (3)
B3—B4—B860.2 (3)Cl1—C15—H15A108.8
B9—B4—B859.8 (3)Cl2—C15—H15A108.8
C2—B4—B659.3 (2)Cl1—C15—H15B108.8
B3—B4—B6106.1 (3)Cl2—C15—H15B108.8
B9—B4—B660.1 (3)H15A—C15—H15B107.7
O2—Ag1—P1—C1028.73 (18)P1—C1—B6—C2107.1 (2)
O2i—Ag1—P1—C10116.12 (17)B5—C1—B6—B740.4 (3)
P2—Ag1—P1—C10115.38 (15)B1—C1—B6—B7107.9 (3)
O2—Ag1—P1—C1148.98 (14)P1—C1—B6—B7116.5 (3)
O2i—Ag1—P1—C1123.63 (14)C2—C1—B6—B7136.4 (3)
P2—Ag1—P1—C14.87 (12)B5—C1—B6—B94.2 (4)
O2—Ag1—P1—C998.64 (18)B7—C1—B6—B936.2 (3)
O2i—Ag1—P1—C911.25 (18)B1—C1—B6—B971.8 (4)
P2—Ag1—P1—C9117.25 (15)P1—C1—B6—B9152.7 (3)
O2—Ag1—P2—C2151.07 (14)C2—C1—B6—B9100.3 (3)
O2i—Ag1—P2—C2125.72 (13)B5—C1—B6—B458.1 (4)
P1—Ag1—P2—C26.15 (11)B7—C1—B6—B498.5 (4)
O2—Ag1—P2—C490.0 (2)B1—C1—B6—B49.4 (4)
O2i—Ag1—P2—C46.79 (19)P1—C1—B6—B4145.0 (3)
P1—Ag1—P2—C4125.08 (17)C2—C1—B6—B438.0 (3)
O2—Ag1—P2—C338.70 (17)B4—C2—B6—C1136.4 (3)
O2i—Ag1—P2—C3121.91 (16)B3—C2—B6—C195.6 (3)
P1—Ag1—P2—C3106.22 (14)B1—C2—B6—C128.7 (3)
C10—P1—C1—B515.7 (3)P2—C2—B6—C1105.4 (3)
C9—P1—C1—B595.0 (3)B4—C2—B6—B798.0 (4)
Ag1—P1—C1—B5143.5 (3)B3—C2—B6—B757.2 (4)
C10—P1—C1—B795.4 (3)B1—C2—B6—B79.7 (4)
C9—P1—C1—B715.4 (4)P2—C2—B6—B7143.8 (3)
Ag1—P1—C1—B7136.8 (3)C1—C2—B6—B738.4 (3)
C10—P1—C1—B6169.9 (3)B4—C2—B6—B936.1 (4)
C9—P1—C1—B659.1 (3)B3—C2—B6—B94.7 (4)
Ag1—P1—C1—B662.4 (3)B1—C2—B6—B971.5 (4)
C10—P1—C1—B160.3 (3)P2—C2—B6—B9154.3 (3)
C9—P1—C1—B1171.0 (3)C1—C2—B6—B9100.2 (4)
Ag1—P1—C1—B167.5 (3)B3—C2—B6—B440.8 (3)
C10—P1—C1—C2125.4 (2)B1—C2—B6—B4107.7 (3)
C9—P1—C1—C2123.8 (2)P2—C2—B6—B4118.2 (3)
Ag1—P1—C1—C22.3 (2)C1—C2—B6—B4136.4 (3)
C10—P1—C9—C1399.3 (3)C2—B4—B6—C142.5 (3)
C1—P1—C9—C13148.0 (3)B3—B4—B6—C15.7 (4)
Ag1—P1—C9—C1334.8 (4)B9—B4—B6—C196.0 (4)
C10—P1—C9—C1127.9 (4)B8—B4—B6—C157.4 (4)
C1—P1—C9—C1184.7 (4)B3—B4—B6—C236.8 (3)
Ag1—P1—C9—C11162.1 (3)B9—B4—B6—C2138.5 (4)
B5—C1—B1—C2137.5 (3)B8—B4—B6—C299.9 (4)
B7—C1—B1—C295.9 (3)C2—B4—B6—B7103.5 (3)
B6—C1—B1—C228.6 (3)B3—B4—B6—B766.7 (4)
P1—C1—B1—C2105.9 (3)B9—B4—B6—B735.0 (4)
B5—C1—B1—B399.1 (3)B8—B4—B6—B73.6 (4)
B7—C1—B1—B357.5 (4)C2—B4—B6—B9138.5 (4)
B6—C1—B1—B39.7 (4)B3—B4—B6—B9101.7 (4)
P1—C1—B1—B3144.2 (3)B8—B4—B6—B938.6 (4)
C2—C1—B1—B338.3 (2)B5—C1—B7—B9101.0 (4)
B5—C1—B1—B236.4 (3)B6—C1—B7—B937.7 (4)
B7—C1—B1—B25.2 (4)B1—C1—B7—B959.6 (5)
B6—C1—B1—B272.5 (4)P1—C1—B7—B9143.4 (3)
P1—C1—B1—B2153.1 (3)C2—C1—B7—B90.6 (4)
C2—C1—B1—B2101.1 (3)B5—C1—B7—B1037.3 (4)
B7—C1—B1—B541.6 (4)B6—C1—B7—B10101.4 (4)
B6—C1—B1—B5108.9 (3)B1—C1—B7—B104.1 (5)
P1—C1—B1—B5116.7 (3)P1—C1—B7—B10152.9 (3)
C2—C1—B1—B5137.5 (3)C2—C1—B7—B1064.3 (4)
C1—B1—C2—B496.4 (3)B6—C1—B7—B5138.7 (3)
B3—B1—C2—B440.1 (3)B1—C1—B7—B541.3 (3)
B2—B1—C2—B43.6 (4)P1—C1—B7—B5115.6 (3)
B5—B1—C2—B459.2 (4)C2—C1—B7—B5101.6 (3)
C1—B1—C2—B3136.4 (3)B5—C1—B7—B6138.7 (3)
B2—B1—C2—B336.5 (3)B1—C1—B7—B697.3 (3)
B5—B1—C2—B399.2 (3)P1—C1—B7—B6105.7 (3)
C1—B1—C2—B628.5 (3)C2—C1—B7—B637.1 (3)
B3—B1—C2—B6108.0 (3)B2—B5—B7—C1100.7 (3)
B2—B1—C2—B671.4 (3)B10—B5—B7—C1138.1 (4)
B5—B1—C2—B68.7 (4)B1—B5—B7—C137.6 (3)
C1—B1—C2—P2106.9 (2)C1—B5—B7—B9100.1 (4)
B3—B1—C2—P2116.7 (3)B2—B5—B7—B90.6 (4)
B2—B1—C2—P2153.2 (3)B10—B5—B7—B938.0 (4)
B5—B1—C2—P2144.1 (3)B1—B5—B7—B962.5 (4)
B3—B1—C2—C1136.4 (3)C1—B5—B7—B10138.1 (4)
B2—B1—C2—C199.9 (3)B2—B5—B7—B1037.4 (3)
B5—B1—C2—C137.2 (3)B1—B5—B7—B10100.5 (4)
C4—P2—C2—B49.0 (4)C1—B5—B7—B636.2 (3)
C3—P2—C2—B4103.3 (3)B2—B5—B7—B664.5 (4)
Ag1—P2—C2—B4136.0 (3)B10—B5—B7—B6101.9 (4)
C4—P2—C2—B388.4 (3)B1—B5—B7—B61.5 (4)
C3—P2—C2—B323.9 (3)C2—B6—B7—C142.6 (3)
Ag1—P2—C2—B3144.6 (3)B9—B6—B7—C1138.2 (4)
C4—P2—C2—B1162.3 (3)B4—B6—B7—C1103.0 (3)
C3—P2—C2—B149.9 (3)C1—B6—B7—B9138.2 (4)
Ag1—P2—C2—B170.7 (2)C2—B6—B7—B995.6 (4)
C4—P2—C2—B668.1 (3)B4—B6—B7—B935.2 (3)
C3—P2—C2—B6179.6 (3)C1—B6—B7—B1099.0 (4)
Ag1—P2—C2—B658.9 (3)C2—B6—B7—B1056.5 (4)
C4—P2—C2—C1133.0 (2)B9—B6—B7—B1039.2 (4)
C3—P2—C2—C1114.7 (2)B4—B6—B7—B104.0 (4)
Ag1—P2—C2—C16.0 (2)C1—B6—B7—B535.6 (3)
B5—C1—C2—B467.0 (4)C2—B6—B7—B57.0 (4)
B7—C1—C2—B40.3 (4)B9—B6—B7—B5102.6 (4)
B6—C1—C2—B440.4 (3)B4—B6—B7—B567.4 (4)
B1—C1—C2—B4106.3 (3)C2—B3—B8—B1064.8 (5)
P1—C1—C2—B4145.8 (3)B4—B3—B8—B10101.5 (4)
B5—C1—C2—B30.5 (4)B2—B3—B8—B1036.9 (4)
B7—C1—C2—B366.8 (3)B1—B3—B8—B102.2 (5)
B6—C1—C2—B3106.8 (3)C2—B3—B8—B90.8 (5)
B1—C1—C2—B339.9 (3)B4—B3—B8—B937.4 (4)
P1—C1—C2—B3147.8 (2)B2—B3—B8—B9101.0 (5)
B5—C1—C2—B139.3 (3)B1—B3—B8—B961.9 (5)
B7—C1—C2—B1106.6 (3)C2—B3—B8—B2101.7 (4)
B6—C1—C2—B1146.7 (3)B4—B3—B8—B2138.4 (4)
P1—C1—C2—B1107.9 (3)B1—B3—B8—B239.1 (3)
B5—C1—C2—B6107.4 (3)C2—B3—B8—B436.6 (3)
B7—C1—C2—B640.1 (3)B2—B3—B8—B4138.4 (4)
B1—C1—C2—B6146.7 (3)B1—B3—B8—B499.3 (3)
P1—C1—C2—B6105.4 (3)B3—B2—B8—B10139.3 (4)
B5—C1—C2—P2144.6 (3)B5—B2—B8—B1036.8 (3)
B7—C1—C2—P2148.1 (3)B1—B2—B8—B10100.5 (4)
B6—C1—C2—P2108.0 (3)B3—B2—B8—B9100.1 (4)
B1—C1—C2—P2105.3 (3)B5—B2—B8—B92.4 (5)
P1—C1—C2—P22.7 (3)B10—B2—B8—B939.2 (4)
C1—P1—C10—C1462.2 (3)B1—B2—B8—B961.3 (5)
C9—P1—C10—C14171.4 (3)B5—B2—B8—B3102.5 (3)
Ag1—P1—C10—C1456.3 (4)B10—B2—B8—B3139.3 (4)
C1—P1—C10—C12177.7 (3)B1—B2—B8—B338.8 (3)
C9—P1—C10—C1268.5 (3)B3—B2—B8—B436.8 (3)
Ag1—P1—C10—C1263.8 (3)B5—B2—B8—B465.6 (4)
C2—B1—B2—B335.6 (3)B10—B2—B8—B4102.4 (4)
C1—B1—B2—B3105.0 (3)B1—B2—B8—B42.0 (5)
B5—B1—B2—B3140.2 (4)C2—B4—B8—B1064.3 (5)
C2—B1—B2—B5104.6 (3)B3—B4—B8—B10101.1 (4)
C1—B1—B2—B535.3 (3)B9—B4—B8—B1036.8 (4)
B3—B1—B2—B5140.2 (4)B6—B4—B8—B102.0 (5)
C2—B1—B2—B83.3 (4)C2—B4—B8—B9101.1 (4)
C1—B1—B2—B866.1 (4)B3—B4—B8—B9137.9 (4)
B3—B1—B2—B838.9 (3)B6—B4—B8—B938.8 (3)
B5—B1—B2—B8101.4 (4)C2—B4—B8—B336.9 (3)
C2—B1—B2—B1065.2 (4)B9—B4—B8—B3137.9 (4)
C1—B1—B2—B104.1 (5)B6—B4—B8—B399.2 (3)
B3—B1—B2—B10100.8 (4)C2—B4—B8—B20.1 (5)
B5—B1—B2—B1039.4 (4)B3—B4—B8—B237.0 (3)
C2—P2—C3—C786.8 (3)B9—B4—B8—B2100.9 (4)
C4—P2—C3—C725.7 (4)B6—B4—B8—B262.2 (4)
Ag1—P2—C3—C7160.3 (3)C1—B7—B9—B863.4 (5)
C2—P2—C3—C6145.7 (3)B10—B7—B9—B835.9 (4)
C4—P2—C3—C6101.9 (3)B5—B7—B9—B82.1 (5)
Ag1—P2—C3—C632.8 (3)B6—B7—B9—B8100.4 (4)
B1—C2—B3—B4138.3 (3)C1—B7—B9—B40.7 (5)
B6—C2—B3—B441.1 (3)B10—B7—B9—B4100.0 (4)
P2—C2—B3—B4116.7 (3)B5—B7—B9—B462.0 (5)
C1—C2—B3—B4101.1 (3)B6—B7—B9—B436.4 (4)
B4—C2—B3—B2100.9 (4)C1—B7—B9—B1099.3 (4)
B1—C2—B3—B237.4 (3)B5—B7—B9—B1038.0 (3)
B6—C2—B3—B259.8 (4)B6—B7—B9—B10136.3 (4)
P2—C2—B3—B2142.4 (3)C1—B7—B9—B637.0 (3)
C1—C2—B3—B20.2 (4)B10—B7—B9—B6136.3 (4)
B4—C2—B3—B837.6 (4)B5—B7—B9—B698.4 (3)
B1—C2—B3—B8100.7 (4)B10—B8—B9—B736.4 (4)
B6—C2—B3—B83.5 (5)B3—B8—B9—B765.8 (5)
P2—C2—B3—B8154.3 (3)B2—B8—B9—B72.8 (5)
C1—C2—B3—B863.5 (4)B4—B8—B9—B7103.0 (4)
B4—C2—B3—B1138.3 (3)B10—B8—B9—B4139.5 (4)
B6—C2—B3—B197.2 (3)B3—B8—B9—B437.2 (4)
P2—C2—B3—B1105.1 (3)B2—B8—B9—B4100.3 (4)
C1—C2—B3—B137.2 (2)B3—B8—B9—B10102.3 (4)
B5—B2—B3—C20.9 (5)B2—B8—B9—B1039.2 (4)
B8—B2—B3—C299.2 (4)B4—B8—B9—B10139.5 (4)
B10—B2—B3—C263.2 (4)B10—B8—B9—B6100.3 (4)
B1—B2—B3—C237.0 (3)B3—B8—B9—B62.0 (6)
B5—B2—B3—B462.5 (4)B2—B8—B9—B661.1 (5)
B8—B2—B3—B437.5 (3)B4—B8—B9—B639.2 (4)
B10—B2—B3—B41.6 (4)C2—B4—B9—B70.5 (5)
B1—B2—B3—B498.7 (3)B3—B4—B9—B762.4 (5)
B5—B2—B3—B8100.0 (4)B8—B4—B9—B7100.0 (5)
B10—B2—B3—B835.9 (3)B6—B4—B9—B736.3 (4)
B1—B2—B3—B8136.2 (4)C2—B4—B9—B899.6 (4)
B5—B2—B3—B136.1 (3)B3—B4—B9—B837.7 (3)
B8—B2—B3—B1136.2 (4)B6—B4—B9—B8136.3 (4)
B10—B2—B3—B1100.2 (4)C2—B4—B9—B1063.7 (4)
C1—B1—B3—C242.4 (3)B3—B4—B9—B101.8 (5)
B2—B1—B3—C2138.5 (3)B8—B4—B9—B1035.9 (4)
B5—B1—B3—C2103.0 (3)B6—B4—B9—B10100.4 (4)
C2—B1—B3—B436.1 (3)C2—B4—B9—B636.7 (3)
C1—B1—B3—B46.3 (4)B3—B4—B9—B698.6 (3)
B2—B1—B3—B4102.4 (4)B8—B4—B9—B6136.3 (4)
B5—B1—B3—B466.9 (4)C1—B6—B9—B735.6 (3)
C2—B1—B3—B2138.5 (3)C2—B6—B9—B7105.1 (3)
C1—B1—B3—B296.1 (3)B4—B6—B9—B7140.2 (4)
B5—B1—B3—B235.4 (3)C1—B6—B9—B865.6 (5)
C2—B1—B3—B899.5 (4)C2—B6—B9—B83.9 (5)
C1—B1—B3—B857.1 (4)B7—B6—B9—B8101.2 (5)
B2—B1—B3—B839.0 (3)B4—B6—B9—B839.0 (4)
B5—B1—B3—B83.5 (4)C1—B6—B9—B4104.6 (3)
C2—P2—C4—C562.1 (4)C2—B6—B9—B435.1 (3)
C3—P2—C4—C5172.1 (3)B7—B6—B9—B4140.2 (4)
Ag1—P2—C4—C555.4 (4)C1—B6—B9—B103.4 (5)
C2—P2—C4—C8177.2 (3)C2—B6—B9—B1066.2 (4)
C3—P2—C4—C867.3 (4)B7—B6—B9—B1039.0 (4)
Ag1—P2—C4—C865.2 (4)B4—B6—B9—B10101.2 (4)
B1—C2—B4—B339.9 (3)B9—B8—B10—B736.0 (4)
B6—C2—B4—B3137.6 (3)B3—B8—B10—B763.7 (5)
P2—C2—B4—B3114.3 (3)B2—B8—B10—B7100.3 (4)
C1—C2—B4—B3100.6 (3)B4—B8—B10—B70.5 (5)
B3—C2—B4—B9100.6 (4)B3—B8—B10—B999.7 (4)
B1—C2—B4—B960.6 (4)B2—B8—B10—B9136.3 (4)
B6—C2—B4—B937.1 (4)B4—B8—B10—B936.5 (4)
P2—C2—B4—B9145.2 (3)B9—B8—B10—B2136.3 (4)
C1—C2—B4—B90.1 (4)B3—B8—B10—B236.6 (4)
B3—C2—B4—B837.6 (3)B4—B8—B10—B299.8 (4)
B1—C2—B4—B82.3 (4)B9—B8—B10—B599.7 (4)
B6—C2—B4—B8100.1 (4)B3—B8—B10—B50.0 (6)
P2—C2—B4—B8151.8 (3)B2—B8—B10—B536.6 (4)
C1—C2—B4—B863.1 (4)B4—B8—B10—B563.1 (5)
B3—C2—B4—B6137.6 (3)C1—B7—B10—B865.2 (5)
B1—C2—B4—B697.7 (3)B9—B7—B10—B836.5 (4)
P2—C2—B4—B6108.1 (3)B5—B7—B10—B8101.3 (4)
C1—C2—B4—B637.0 (3)B6—B7—B10—B82.8 (5)
B2—B3—B4—C2100.4 (3)C1—B7—B10—B9101.7 (4)
B8—B3—B4—C2137.7 (4)B5—B7—B10—B9137.9 (4)
B1—B3—B4—C236.7 (3)B6—B7—B10—B939.3 (3)
C2—B3—B4—B9100.2 (3)C1—B7—B10—B21.2 (6)
B2—B3—B4—B90.1 (4)B9—B7—B10—B2100.5 (5)
B8—B3—B4—B937.5 (3)B5—B7—B10—B237.4 (4)
B1—B3—B4—B963.5 (4)B6—B7—B10—B261.2 (5)
C2—B3—B4—B8137.7 (4)C1—B7—B10—B536.2 (3)
B2—B3—B4—B837.4 (3)B9—B7—B10—B5137.9 (4)
B1—B3—B4—B8101.0 (4)B6—B7—B10—B598.6 (3)
C2—B3—B4—B637.1 (3)B7—B9—B10—B8139.5 (4)
B2—B3—B4—B663.2 (4)B4—B9—B10—B836.4 (3)
B8—B3—B4—B6100.6 (4)B6—B9—B10—B8100.4 (4)
B1—B3—B4—B60.4 (4)B8—B9—B10—B7139.5 (4)
B7—C1—B5—B299.8 (4)B4—B9—B10—B7103.1 (4)
B6—C1—B5—B259.7 (4)B6—B9—B10—B739.0 (3)
B1—C1—B5—B237.3 (3)B7—B9—B10—B2100.3 (4)
P1—C1—B5—B2145.5 (3)B8—B9—B10—B239.1 (3)
C2—C1—B5—B21.0 (4)B4—B9—B10—B22.7 (5)
B6—C1—B5—B740.1 (3)B6—B9—B10—B261.3 (5)
B1—C1—B5—B7137.1 (3)B7—B9—B10—B537.5 (3)
P1—C1—B5—B7114.7 (3)B8—B9—B10—B5102.0 (4)
C2—C1—B5—B7100.8 (3)B4—B9—B10—B565.6 (5)
B7—C1—B5—B1036.8 (3)B6—B9—B10—B51.6 (5)
B6—C1—B5—B103.3 (4)B3—B2—B10—B836.4 (3)
B1—C1—B5—B10100.3 (4)B5—B2—B10—B8139.1 (4)
P1—C1—B5—B10151.5 (3)B1—B2—B10—B899.6 (4)
C2—C1—B5—B1064.0 (4)B3—B2—B10—B765.1 (5)
B7—C1—B5—B1137.1 (3)B5—B2—B10—B737.5 (4)
B6—C1—B5—B197.0 (3)B8—B2—B10—B7101.5 (5)
P1—C1—B5—B1108.2 (3)B1—B2—B10—B71.9 (6)
C2—C1—B5—B136.3 (3)B3—B2—B10—B92.6 (5)
B3—B2—B5—C11.2 (5)B5—B2—B10—B9100.0 (4)
B8—B2—B5—C162.5 (4)B8—B2—B10—B939.1 (4)
B10—B2—B5—C198.7 (4)B1—B2—B10—B960.5 (5)
B1—B2—B5—C137.1 (3)B3—B2—B10—B5102.6 (4)
B3—B2—B5—B762.6 (4)B8—B2—B10—B5139.1 (4)
B8—B2—B5—B71.2 (4)B1—B2—B10—B539.4 (3)
B10—B2—B5—B737.3 (3)C1—B5—B10—B864.7 (5)
B1—B2—B5—B798.5 (3)B2—B5—B10—B837.0 (4)
B3—B2—B5—B1099.9 (4)B7—B5—B10—B8100.9 (5)
B8—B2—B5—B1036.2 (4)B1—B5—B10—B82.1 (5)
B1—B2—B5—B10135.8 (4)C1—B5—B10—B736.2 (3)
B3—B2—B5—B135.9 (3)B2—B5—B10—B7137.9 (4)
B8—B2—B5—B199.7 (4)B1—B5—B10—B798.8 (4)
B10—B2—B5—B1135.8 (4)C1—B5—B10—B90.9 (5)
C2—B1—B5—C141.4 (3)B2—B5—B10—B9100.8 (4)
B3—B1—B5—C1102.8 (3)B7—B5—B10—B937.1 (4)
B2—B1—B5—C1138.3 (4)B1—B5—B10—B961.7 (4)
C2—B1—B5—B296.9 (4)C1—B5—B10—B2101.7 (4)
C1—B1—B5—B2138.3 (4)B7—B5—B10—B2137.9 (4)
B3—B1—B5—B235.5 (3)B1—B5—B10—B239.1 (3)
C2—B1—B5—B74.5 (4)O1—N1—O2—Ag1172.7 (3)
C1—B1—B5—B736.9 (3)O3—N1—O2—Ag15.6 (5)
B3—B1—B5—B765.8 (4)O1—N1—O2—Ag1i16.1 (5)
B2—B1—B5—B7101.4 (4)O3—N1—O2—Ag1i165.6 (3)
C2—B1—B5—B1057.9 (4)O2i—Ag1—O2—N1172.6 (4)
C1—B1—B5—B1099.3 (4)P1—Ag1—O2—N156.7 (3)
B3—B1—B5—B103.5 (4)P2—Ag1—O2—N177.4 (3)
B2—B1—B5—B1039.0 (4)O2i—Ag1—O2—Ag1i0.0
B5—C1—B6—C296.1 (3)P1—Ag1—O2—Ag1i115.89 (11)
B7—C1—B6—C2136.4 (3)P2—Ag1—O2—Ag1i109.99 (11)
B1—C1—B6—C228.5 (3)
Symmetry code: (i) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C15—H15A···O3i0.972.483.203 (6)132
C15—H15A···O1i0.972.483.389 (8)155
Symmetry code: (i) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C15—H15A···O3i0.972.483.203 (6)132
C15—H15A···O1i0.972.483.389 (8)155
Symmetry code: (i) x+1, y, z.
 

Acknowledgements

This work was supported by the Natural Science Foundation of China, National Ministry of Science and Technology of China (grant No. 2012CB224801).

References

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