Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 5 (May 2014)


metal-organic compounds



ds2238 scheme

Acta Cryst. (2014). E70, m178    [ doi:10.1107/S1600536814007533 ]

1,4-Diazo­niabi­cyclo­[2.2.2]octane tetra­chlorido­cadmate(II) monohydrate

T. Ben Rhaiem and H. Boughzala

Abstract: The asymmetric unit of the title compound (C6H14N2)[CdCl4]·H2O contained one 1,4-di­aza­bicyclo­[2.2.2]octane dication, a tetrahedral CdCl42- anion and a lattice water mol­ecule. In the crystal, the solvate water mol­ecule inter­acts with the cationic and anionic species via N-H...O and O-H...Cl [O...Cl = 3.289 (7) Å] hydrogen-bond inter­actions, respectively, leading to a layered supramolecular structure extending parallel to (011).

CCDC reference: 967916


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