Acta Cryst. (2014). E70, o522 [ doi:10.1107/S160053681400720X ]
Abstract: In the title molecular salt, C22H21FI+·CF3SO3-, the dihedral angle between the rings of the biphenyl group is 65.6 (1)°. The ring of the mesitylene group is inclined to the fluorobenzene ring at an angle of 86.1 (3)° and the C-I-C bond angle is 97.0 (2)°. In the crystal, extremely short IO contacts of 2.862 (5) and 2.932 (5) Å occur, due to the strong electrostatic interactions between the I atom and two adjacent trifluoromethanesulfonate counter-ions. There are also C-HF and C-H interactions present: together with the IO bonds, these result in a three-dimensional network.
CCDC reference: 994798
Hyper-Text Markup Language (HTML) file
Chemdraw file (4.1 kbytes)
Chemical Markup Language (CML) file (8.3 kbytes)
To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.
The download button will force most browsers to prompt for a file name to store the data on your hard disk.
Where possible, images are represented by thumbnails.
Copyright © International Union of Crystallography