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Acta Cryst. (2014). E70, m190-m191
[ doi:10.1107/S1600536814009064 ]

Bis(2,2'-bipyridyl-[kappa]2N,N')chloridonickel(II) nitrate trihydrate

M. Boutebdja, A. Beghidja, C. Beghidja, Z. Setifi and H. Merazig

Abstract: In the title hydrated salt, [NiCl(C10H8N2)2](NO3)·3H2O, the Ni2+ ion is coordinated by two 2,2'-bipyridyl (2,2'-bpy) ligands and a chloride ion in a trigonal-bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2'-bpy ring systems is 72.02 (6)°. In the crystal, the components are linked by C-H...O and O-H...O hydrogen bonds and aromatic [pi]-[pi] stacking inter­actions [shortest centroid-centroid separation = 3.635 (2) Å], generating a three-dimensional network.


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