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Volume 70 
Part 5 
Pages m190-m191  
May 2014  

Received 20 April 2014
Accepted 22 April 2014
Online 26 April 2014

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.005 Å
R = 0.044
wR = 0.127
Data-to-parameter ratio = 17.4
Details
Open access

Bis(2,2'-bipyridyl-[kappa]2N,N')chloridonickel(II) nitrate trihydrate

aUnité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria, and bDépartement de Technologie, Faculté de Technologie, Université 20 Août 1955-Skikda, BP 26, Route d'El-Hadaiek, Skikda 21000, Algeria
Correspondence e-mail: a_beghidja@yahoo.fr, setifi_zouaoui@yahoo.fr

In the title hydrated salt, [NiCl(C10H8N2)2](NO3)·3H2O, the Ni2+ ion is coordinated by two 2,2'-bipyridyl (2,2'-bpy) ligands and a chloride ion in a trigonal-bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2'-bpy ring systems is 72.02 (6)°. In the crystal, the components are linked by C-H...O and O-H...O hydrogen bonds and aromatic [pi]-[pi] stacking inter­actions [shortest centroid-centroid separation = 3.635 (2) Å], generating a three-dimensional network.

Related literature

For the isotypic copper complex, see: Harrison et al. (1981[Harrison, W. D., Kennedy, D. M., Power, M., Sheahan, R. & Hathaway, B. J. (1981). J. Chem. Soc. Dalton Trans. pp. 1556-1564.]); Liu et al. (2004[Liu, H., Liu, C. & Zhong, B. (2004). Chem. J. Internet. 6, 44.]). For related structures, see: Martens et al. (1996[Martens, C. F., Schenning, A. P. H. J., Feiters, M. C., Beurskens, G., Smits, J. M. M., Beurskens, P. T., Smeets, W. J. J., Spek, A. L. & Nolte, R. J. M. (1996). Supramol. Chem. 8, 31-44.]); Gao & Li (2009[Gao, Z. & Li, F. (2009). Acta Cryst. E65, m1664.])

[Scheme 1]

Experimental

Crystal data
  • [NiCl(C10H8N2)2](NO3)·3H2O

  • Mr = 522.57

  • Monoclinic, P 21 /n

  • a = 8.2341 (2) Å

  • b = 21.1920 (5) Å

  • c = 13.1284 (4) Å

  • [beta] = 99.722 (1)°

  • V = 2257.97 (10) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.03 mm-1

  • T = 296 K

  • 0.15 × 0.13 × 0.10 mm

Data collection
  • Bruker APEXII CCD diffractometer

  • 21125 measured reflections

  • 5177 independent reflections

  • 3811 reflections with I > 2[sigma](I)

  • Rint = 0.034

Refinement
  • R[F2 > 2[sigma](F2)] = 0.044

  • wR(F2) = 0.127

  • S = 1.01

  • 5177 reflections

  • 298 parameters

  • 9 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 0.47 e Å-3

  • [Delta][rho]min = -0.47 e Å-3

Table 1
Selected bond lengths (Å)

Ni1-Cl1 2.3035 (9)
Ni1-N1 1.989 (2)
Ni1-N2 2.088 (2)
Ni1-N3 2.107 (2)
Ni1-N4 1.983 (2)

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O1W-H1W...O3Wi 0.81 2.29 2.876 (6) 129
O1W-H2W...O2ii 0.83 2.18 2.934 (7) 151
O2W-H3W...O2ii 0.84 1.90 2.723 (7) 166
O2W-H4W...Cl1i 0.83 2.47 3.245 (4) 155
O3W-H5W...O2Wiii 0.85 1.88 2.699 (6) 161
O3W-H6W...O1iv 0.83 2.03 2.839 (7) 165
C14-H14...O2W 0.93 2.56 3.424 (5) 155
C18-H18...O1W 0.93 2.39 3.257 (6) 156
Symmetry codes: (i) -x, -y, -z; (ii) x, y, z-1; (iii) -x+1, -y, -z; (iv) [-x+{\script{1\over 2}}, y-{\script{1\over 2}}, -z+{\script{1\over 2}}].

Data collection: APEX2 (Bruker, 2006[Bruker (2006). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2006[Bruker (2006). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ATOMS (Dowty, 1995[Dowty, E. (1995). ATOMS. Shape Software, Kingsport, Tennessee, USA.]); software used to prepare material for publication: WinGX publication routines (Farrugia, 2012[Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.]).


Supporting information for this paper is available from the IUCr electronic archives (Reference: HB7220 ).


Acknowledgements

The authors thank the MESRS (Algeria) for financial support. MB thanks the DG-RSDT and ANDRU (Direction Générale de la Recherche Scientifique et du Dévelopement Technologique et l'Agence Nationale pour le Développement de la Recherche Universitaire, Algeria) through the PNR project.

References

Bruker (2006). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Dowty, E. (1995). ATOMS. Shape Software, Kingsport, Tennessee, USA.
Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Gao, Z. & Li, F. (2009). Acta Cryst. E65, m1664.  [CSD] [CrossRef] [IUCr Journals]
Harrison, W. D., Kennedy, D. M., Power, M., Sheahan, R. & Hathaway, B. J. (1981). J. Chem. Soc. Dalton Trans. pp. 1556-1564.  [CSD] [CrossRef]
Liu, H., Liu, C. & Zhong, B. (2004). Chem. J. Internet. 6, 44.
Martens, C. F., Schenning, A. P. H. J., Feiters, M. C., Beurskens, G., Smits, J. M. M., Beurskens, P. T., Smeets, W. J. J., Spek, A. L. & Nolte, R. J. M. (1996). Supramol. Chem. 8, 31-44.  [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]


Acta Cryst (2014). E70, m190-m191   [ doi:10.1107/S1600536814009064 ]

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