Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 5 (May 2014)

metal-organic compounds

hy2643 scheme

Acta Cryst. (2014). E70, m183    [ doi:10.1107/S1600536814006771 ]


D. Pandey, S. S. Narvi, G. K. Mehrotra and R. J. Butcher

Abstract: In the title complex, [Ni(NCS)2(C6H6N2O)2(H2O)2], the NiII ion is located on an inversion center and is coordinated in a distorted octa­hedral environment by two N atoms from two nicotinamide ligands and two water mol­ecules in the equatorial plane, and two N atoms from two thio­cyanate anions in the axial positions, all acting as monodentate ligands. In the crystal, weak N-H...S hydrogen bonds between the amino groups and the thio­cyanate anions form an R42(8) motif. The complex mol­ecules are linked by O-H...O, O-H...S, and N-H...S hydrogen bonds into a three-dimensional supra­molecular structure. Weak [pi]-[pi] inter­actions between the pyridine rings is also found [centroid-centroid distance = 3.8578 (14) Å].

CCDC reference: 993930

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (61.2 kbytes)
[ doi:10.1107/S1600536814006771/hy2643sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster