Acta Cryst. (2014). E70, m195
[ doi:10.1107/S1600536814009027 ]
Abstract: In the title compound, [Ni(C15H14N3O2S)2], the NiII atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The NiII atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete complex molecules are linked by weak N-HO hydrogen bonds, generating chains along . The chains are further connected via weak O-HN interactions into a layered network extending parallel to (001).
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