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Acta Cryst. (2014). E70, m195
[ doi:10.1107/S1600536814009027 ]

Bis(4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazonato-N1,S)nickel(II)

A. B. de Oliveira, B. R. S. Feitosa, C. Näther and I. Jess

Abstract: In the title compound, [Ni(C15H14N3O2S)2], the NiII atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The NiII atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete complex mol­ecules are linked by weak N-H...O hydrogen bonds, generating chains along [110]. The chains are further connected via weak O-H...N inter­actions into a layered network extending parallel to (001).


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