Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 5 (May 2014)

metal-organic compounds

rz5113 scheme

Acta Cryst. (2014). E70, m170-m171    [ doi:10.1107/S1600536814007235 ]

Poly[[tetra-[mu]-cyanido-[kappa]8C:N-dodeca-cyanido-[kappa]12C-tris­(N,N-di­methyl­formamide-[kappa]O)tris­(methanol-[kappa]O)tris­(3,4,7,8-tetra­methyl-1,10-phenanthroline-[kappa]2N,N')trimanganese(II)ditungstate(V)] dihydrate]

F.-L. Yang and D. Yang

Abstract: The asymmetric unit of the title compound, {[Mn3{W(CN)8}2(C16H16N2)3(C3H7NO)3(CH3OH)3]·2H2O}n, consists of three [Mn(N,N-di­methyl­formamide)(methanol)(3,4,7,8-tetra­methyl-1,10-phenanthroline)]2+ cations, two [W(CN)8]3- anions and two water mol­ecules. Each water mol­ecule is disordered over three sets of sites, with a refined occupancy ratio of 0.310 (9):0.275 (9):0.415 (9) for one mol­ecule and 0.335 (9):0.288 (9):0.377 (9) for the other mol­ecule. The MnII atoms exhibit a distorted octa­hedral geometry, while the WV atoms adopt a distorted square-anti­prismatic geometry. The MnII and WV atoms are linked alternatively through cyanide groups, forming a tetra­nuclear 12-atom rhombic metallacycle. Adjacent metallacycles are further connected by [mu]2-bridging cyanide anions, generating a 3,2-chain structure running parallel to [101]. Inter­chain [pi]-[pi] inter­actions are observed [centroid-centroid distances = 3.763 (3) and 3.620 (2) Å].

CCDC reference: 994877

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