Acta Cryst. (2014). E70, m162-m163 [ doi:10.1107/S1600536814006060 ]
Abstract: The title compound, [Dy4(C7H4NO4)12(C11H9N5)2] or Dy4(L1)12(L2)2, where HL1 = 3-nitrobenzoic acid and HL2 = 2,6-bis(1H-pyrazol-1-y1)pyridine, is a linear tetranuclear complex possessing inversion symmetry. The two central inversion-related DyIII atoms are seven-coordinate, DyO7, with a monocapped triangular-prismatic geometry. The outer two DyIII atoms are eight-coordinate, DyO5N3, with a bicapped triangular-prismatic geometry. The outer adjacent DyIII atoms are bridged by three L1- carboxylate groups, while the inner inversion-related DyIII atoms are bridged by four L1- carboxylate groups. The L2 ligands are terminally coordinated to the outer DyIII atoms in a tridentate manner. In the crystal, molecules are linked via C-HO hydrogen bonds, forming a two-dimensional network parallel to (001). Two carboxylate O atoms, and N and O atoms of three nitro groups, are disordered over two positions, with a refined occupancy ratio of 0.552 (6):0.448 (6).
CCDC reference: 992494
Hyper-Text Markup Language (HTML) file (190.4 kbytes)
To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.
The download button will force most browsers to prompt for a file name to store the data on your hard disk.
Where possible, images are represented by thumbnails.
Copyright © International Union of Crystallography