[Open access]

[Contents scheme]

Acta Cryst. (2014). E70, o584-o585
[ doi:10.1107/S1600536814007636 ]

O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyl­oxazolidin-3-yl]propan-2-yl} carbonodi­thio­ate

J. P. García-Merinos, H. López-Ruiz, Y. López and S. Rojas-Lima

Abstract: In the title compound, C15H17NO4S2, synthesized by addition of O-ethylxanthic acid potassium salt to a diastereomeric mixture of (4R)-3-(2-chloro­propano­yl)-4-phenyl­oxazolidin-2-one, the oxazolidinone ring has a twist conformation on the C-C bond. The phenyl ring is inclined to the mean plane of the oxazolidinone ring by 76.4 (3)°. In the chain the methine H atom is involved in a C-H...S and a C-H...O intra­molecular inter­action. In the crystal, mol­ecules are linked by C-H...[pi] inter­actions, forming chains along [001]. The S configuration at the C atom to which the xanthate group is attached was determined by comparison to the known R configuration of the C atom to which the phenyl group is attached.

Copyright © International Union of Crystallography
IUCr Webmaster