Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 5 (May 2014)


organic compounds



tk5302 scheme

Acta Cryst. (2014). E70, o537-o538    [ doi:10.1107/S1600536814007806 ]

Bis{2-[(Tri­phenyl­meth­yl)amino]­phen­yl} diselenide aceto­nitrile monosolvate

A. Neuba, T. Schneider, U. Flörke and G. Henkel

Abstract: The mol­ecular structure of the title compound, C50H40N2Se2·C2H3N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se-Se bond length of 2.3529 (6) Å and a C-Se-Se-C torsion angle of 93.53 (14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42 (16)°. Intra­molecular N-H...Se hydrogen bonds are noted. Inter­molecular C-H...Se inter­actions give rise to supra­molecular chains extended along [100]. One severely disordered aceto­nitrile solvent mol­ecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009). Acta Cryst. D65, 148-155]; the crystal data take the presence of this mol­ecule into account.

CCDC reference: 996016


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536814007806/tk5302sup0.html ]
Supplementary materials


cmldisplay filedownload file

Chemical Markup Language (CML) file (14.3 kbytes)
[ doi:10.1107/S1600536814007806/tk5302Isup3.cml ]
Supplementary material


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster