Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 5 (May 2014)


metal-organic compounds



xu5742 scheme

Acta Cryst. (2014). E70, m189    [ doi:10.1107/S1600536814008083 ]

Poly[([mu]3-3,5-diisopropyl-4H-1,2,4-triazolato-[kappa]3N:N':N'')silver(I)]

G.-G. Cui, X.-X. Yang, J.-P. Yang and X. Jiang

Abstract: In the polymeric title compound, [Ag(C8H14N3)]n, the AgI cation is coordinated by three N atoms from three 3,5-diisopropyl-1,2,4-triazolate anions in a T-shaped geometry. The AgI cation deviates from the coordination plane by 0.014 (1) Å and the N-Ag-N bond angles are 96.85 (11), 97.72 (10) and 165.39 (12)°. The triazolate anion bridges three AgI cations, forming a three-dimensional polymeric network.

CCDC reference: 996628


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