Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 5 (May 2014)

organic compounds

zp2012 scheme

Acta Cryst. (2014). E70, o524-o525    [ doi:10.1107/S1600536814007387 ]

{(3aR,5S,6R,6aR)-5-[(R)-1,2-Di­hydroxy­eth­yl]-2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxol-6-yl}methyl methane­sulfonate

V. Rjabovs, A. Mishnev, G. Kiselovs and M. Turks

Abstract: In the title compound, C11H20O8S, the furan­ose ring has a pseudorotation phase angle equal to 31.3° and assumes a 3T4 conformation, with deviations of 0.297 (4) and -0.152 (4) Å for the corresponding C atoms. The dioxolane ring adopts an envelope conformation. One of the O atoms is at the flap and deviates from the least-squares plane formed by the other four ring atoms by 0.405 (2) Å. The dihedral angle between the planar fragments of the rings is 63.53 (8)°. In the crystal, mol­ecules are associated into sheets perpendiculer to the b axis by means of O-H...O hydrogen bonds. A few weak C-H...O inter­actions are also observed.

CCDC reference: 995085

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (69.7 kbytes)
[ doi:10.1107/S1600536814007387/zp2012sup0.html ]
Supplementary materials

cmldisplay filedownload file

Chemical Markup Language (CML) file (6.5 kbytes)
[ doi:10.1107/S1600536814007387/zp2012Isup3.cml ]
Supplementary material


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster