Acta Crystallographica Section E

Structure Reports Online

Volume 70, Part 5 (May 2014)


metal-organic compounds



zs2293 scheme

Acta Cryst. (2014). E70, m173    [ doi:10.1107/S1600536814007077 ]

Di­chlorido­(4-{[(quinolin-2-yl)methyl­idene]amino}phenol-[kappa]2N,N')mercury(II)

M. S. H. Faizi and P. Sen

Abstract: In the mononuclear title complex, [HgCl2(C16H12N2O)], synthesized from the phenolic Schiff base 4-[(quinolin-2-yl­methyl­idene)amino]­phenol (QMAP), the coordination geometry around Hg2+ is distorted tetra­hedral, comprising two Cl atoms [Hg-Cl = 2.3565 (12) and 2.5219 (12) Å] and two N-atom donors from the QMAP ligand, viz. one imine and the other quinoline [Hg-N = 2.392 (2) and 2.237 (2) Å, respectively]. In the crystal, O-H...Cl hydrogen bonds generate a chain structure extending along the c-axis direction. Weak C-H...Cl and [pi]-[pi] stacking inter­actions [minimum ring centroid separation = 3.641 (3) Å] give an overall layered structure lying parallel to (001).

CCDC reference: 994407


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