Journal of Applied Crystallography

Volume 35, Part 1 (February 2002)



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J. Appl. Cryst. (2002). 35, 108-112    [doi:10.1107/S0021889801019914]

Structure, crystal growth and physical anisotropy of KYb(WO4)2, a new laser matrix

M. C. Pujol, X. Mateos, M. A. R. Solé, J. Massons, J. Gavaldà, X. Solans, F. Díaz and M. Aguiló

Abstract: The crystal structure of monoclinic KYb(WO4)2 (KYbW) crystals has been refined (in space group C2/c) at room temperature by using single-crystal X-ray diffraction data. KYbW undoped crystals were grown by the TSSG (top-seeded-solution growth) slow-cooling method. The crystals show {110}, {\bar{1}11}, {010} and {310} faces, which basically define their habit. The linear thermal expansion tensor has been determined and the principal axis with maximum thermal expansion (\alpha ^{\,\prime}_{33} = 16.68 × 10-6  K-1), {\bf X}^{\,\prime}_{3}, was located 12° from the c axis. Its principal {\bf X}^{\,\prime}_{1}, {\bf X}^{\,\prime}_{2} and {\bf X}^{\,\prime}_{3} axes are [302], [010] and [106] directions, respectively, in the crystallographic system. The optical tensor has been studied at [bold lambda] = 632.8  nm at room temperature; two principal axes, Ng and Nm, are located in the ac plane, while the other, Np, is parallel to [010]. The principal axis with maximum refractive index (ng = 2.45), Ng, was located 19° from the c axis.

Online 22 January 2002


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