Fe K-edge XANES database: read me
==================================

- All samples are natural unless specified otherwise.

- Spectra were recorded at beamline 10.3.2 of the Advanced Light Source, Lawrence Berkeley National Lab, 
Berkeley, CA- USA,  using a two-crystal Si(111) monochromator (fixed exit), unless specified otherwise.

- All 10.3.2 spectra were acquired either in fluorescence mode using a 7 element Ge solid state detector with XIA Camac electronics.
or in transmission mode using an atmospheric N2 ionization chamber.

- All data were recorded at room temperature.

- The Fe XANES spectra were calibrated, background substracted and normalized using standard procedures (Manceau et al. 2002) and
 a suite of LabVIEW XAS programs available at ALS beamline 10.3.2 (http://xraysweb.lbl.gov/uxas/Beamline/Software/Software.htm).

- The energy calibration was performed using an Fe foil (Fe-K edge at 7110.75eV, Kraft et al. (1996) Rev. Sci. Instr. 67:681-687) 

- For non-cubic minerals polarization effects on the fine structure shape of the spectra may be important (Manceau et al. 2002) so 
spectra were collected on various grains with different orientations. We report spectra from a principal components analysis (PCA) 
as reference spectra. We used an Iterative Target-Factor Analysis (ITFA) (see Scheinost, et. al., Physica Scripta (2005) 115, 1038),
an extension to PCA in which linear combinations of the PCA abstract components are formed in such a way that the resulting ITFA 
components are all positive, and loading numbers of the individual spectra are as different as possible from each other. 
The number of components used is the smallest consistent with the data, and no larger than what is dictated by the crystal symmetry.
 The result of ITFA is a set of spectra which often look very much like the underlying physical species. The ITFA method is fully 
described in A. Rossberg, T. Reich, G. Bernhard. Anal. Bioanal. Chem (2003) 376:631-638.

- Some of the spectra collected on Fe "hot" particles were corrected for overabsorption effects when possible using the transmission data.

- Data recording dates are in a "mm/dd/yr" format
 
- We are grateful to the following contributors to this database:

	Deborah L. Bond
	Thomas Borch
	Benjamin C. Bostick
	Tonio Buonassisi
	Marc Burchell
	Anna Butterworth
	Clara S. Chan
	Scott Fendorf
	Colleen Hansel
	Matthias Heuer
	Anthony Kearsley 
	Chris S. Kim
	Matt Newville
	Peter Nico
	Peggy O'Day
	Nelson Rivera
	Kent Ross 
	Cara Santelli 
	Brandy Toner
	Glenn A. Waychunas 

Database compiled by S. Fakra on Aug. 14th, 2008.

The operations of the Advanced Light Source at Lawrence Berkeley National Laboratory are supported by the
Director, Office of Science, Office of Basic Energy Sciences, US Department of Energy under
contract No. DE-AC02-05CH11231.




#%Name: Aegirine ITFA component 0
#%Empirical formula: NaFe3+(Si2O6)/ Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts).
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed. Transmission data were used to correct for overabsorption effects.
#%Temp: Room temp (28 degC)
#%Time&date: 9:06 PM 03/14/2007
#%Provider: Matthew A. Marcus, Sirine Fakra.
#%============================================================
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#%Name: Aegirine ITFA component 1
#%Empirical formula: NaFe3+(Si2O6)/ Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts).
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed. Transmission data were used to correct for overabsorption effects.
#%Temp: Room temp (28 degC)
#%Time&date: 9:06 PM 03/14/2007
#%Provider: Matthew A. Marcus, Sirine Fakra.
#%============================================================
7.0106674E+3 1.7440343E-3
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7.4096573E+3 1.0048599E+0




#%Name: Aegirine powder average
#%Empirical formula: NaFe3+(Si2O6)/ Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts).
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed. Transmission data were used to correct for overabsorption effects.
#%Temp: Room temp (28 degC)
#%Time&date: 9:06 PM 03/14/2007
#%Provider: Matthew A. Marcus, Sirine Fakra.
#%============================================================
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#%Name: Akaganeite
#%Empirical formula: beta-Fe3+OOH
#%Mineral group: oxyhydroxides
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 60x20 um
#%Det:  I0=N2, Transmission mode (ionization chamber). 
#%Ref/notes:  XRD confirmed
#%Temp: Room temp (28 degC)
#%Time&date: 4:26 AM 2/4/2004
#%Provider: Sirine Fakra, Clara S. Chan.
#%============================================================
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6.9402451E+3 3.6335240E-4
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#%Name: Almandine
#%Empirical formula: Fe2+3Al2(SiO4)3 / Webmineral
#%Mineral group: garnet
#%Xtal system: cubic
#%Edge: K
#%Sample prep: 
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  none
#%Temp: Room temp (28 degC)
#%Time&date: 8:13 AM 2/19/2006
#%Provider: Glenn A. Waychunas, Matthew A. Marcus.
#%============================================================
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#%Name: Andratite
#%Empirical formula: Ca3Fe2+2(SiO4)3  / Webmineral
#%Mineral group: garnet
#%Xtal system: cubic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28 degC)
#%Time&date: 5:30 PM 08/04/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: AT11 seafloor basalt Glass
#%Empirical formula: 
#%Mineral group: 
#%Xtal system: 
#%Edge: K
#%Sample prep: 30 um thin section on glass slide, Spectrum Petrographics Inc.
#%Beamline: ALS 10.3.2, HxV slits = 100x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  none
#%Temp: Room temp (28 degC)
#%Time&date: 8:39 PM 2/8/2006
#%Provider: Cara Santelli, Brandy M. Toner.
#%============================================================
7.0137871E+3 1.4739381E-3
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#%Name: Augite
#%Empirical formula: Ca0.9Na0.1Mg0.9Fe2+0.2Al0.4Ti0.1Si1.9O6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: 
#%Beamline: SSRL
#%Det:  transmission mode
#%Ref/notes: Stanford Mineral Collection. Raman confirmed.
#%Temp: Room temp
#%Time&date: 
#%Provider: Thomas Borch, Colleen Hansel, Scott Fendorf.
#%===================================================================
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#%Name: Augite powder average
#%Empirical formula: Ca0.9Na0.1Mg0.9Fe2+0.2Al0.4Ti0.1Si1.9O6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: 
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the Natural History Museum, London, UK. XRD confirmed. Substrate background was substracted
#%Temp: Room temp (28 degC)
#%Time&date: 12:41 PM 12/20/2007
#%Provider: Anna Buttherworth, Sirine Fakra, Matthew A. Marcus. 
#%===================================================================
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7.3966566E+3 9.9888292E-1




#%Name: Augite ITFA component 0
#%Empirical formula: Ca0.9Na0.1Mg0.9Fe2+0.2Al0.4Ti0.1Si1.9O6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 300x50 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the Natural History Museum, London, UK. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:41 AM 08/14/2006
#%Provider: Anna Buttherworth, Matthew A. Marcus, Sirine Fakra.
#%=============================================================
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7.4056504E+3 9.8147181E-1




#%Name: Augite ITFA component 1
#%Empirical formula: Ca0.9Na0.1Mg0.9Fe2+0.2Al0.4Ti0.1Si1.9O6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 300x50 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the Natural History Museum, London, UK. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:41 AM 08/14/2006
#%Provider: Anna Buttherworth, Matthew A. Marcus, Sirine Fakra.
#%=============================================================
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7.4031499E+3 9.9697660E-1
7.4056504E+3 9.9879423E-1




#%Name: Augite ITFA component 2
#%Empirical formula: Ca0.9Na0.1Mg0.9Fe2+0.2Al0.4Ti0.1Si1.9O6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 300x50 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the Natural History Museum, London, UK. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:41 AM 08/14/2006
#%Provider: Anna Buttherworth, Matthew A. Marcus, Sirine Fakra.
#%=============================================================
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7.4006494E+3 9.9940919E-1
7.4031499E+3 1.0044816E+0
7.4056504E+3 1.0034825E+0




#%Name: Augite ITFA component 3
#%Empirical formula: Ca0.9Na0.1Mg0.9Fe2+0.2Al0.4Ti0.1Si1.9O6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 300x50 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the Natural History Museum, London, UK. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:41 AM 08/14/2006
#%Provider: Anna Buttherworth, Matthew A. Marcus, Sirine Fakra.
#%=============================================================
7.0195818E+3 1.5545890E-3
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7.0395852E+3 1.9390134E-3
7.0445861E+3 1.9174689E-3
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7.0645896E+3 3.0372072E-3
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#%Name: Awaruite
#%Empirical formula: Ni2.5Fe0+ / Webmineral
#%Mineral group: metal
#%Xtal system: cubic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28 degC)
#%Time&date: 7:21 PM 2/24/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Biotite
#%Empirical formula: KMg2.5Fe2+0.5AlSi3O10(OH)1.75F0.25 / Webmineral
#%Mineral group: phyllosilicate, mica
#%Xtal system: monoclinic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 300x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by Kent Ross, EPS, Mineral Collection, UC berkeley, CA, USA. XRD confirmed.
#%Temp: Room temp (28 degC)
#%Time&date: 6:33 AM 6/21/2007
#%Provider: Sirine Fakra, Matthew A. Marcus, Kent Ross.
#%============================================================
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#%Name: Chromite
#%Empirical formula: Fe2+Cr2O4  / Webmineral
#%Mineral group: spinel, oxides
#%Xtal system: cubic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 70x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  none
#%Temp: Room temp (28 degC)
#%Time&date: 12:34 AM 2/25/2007
#%Provider: Peter Nico, Matthew A. Marcus, Sirine Fakra.
#%============================================================
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#%Name: Cubanite ITFA component 0
#%Empirical formula: CuFe2+2S3  / Webmineral
#%Mineral group: sulfides
#%Xtal system: Orthorhombic 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 6:10 AM 2/24/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Cubanite ITFA component 1
#%Empirical formula: CuFe2+2S3  / Webmineral
#%Mineral group: sulfides
#%Xtal system: Orthorhombic 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 6:10 AM 2/24/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Cubanite powder average
#%Empirical formula: CuFe2+2S3  / Webmineral
#%Mineral group: sulfides
#%Xtal system: Orthorhombic 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 6:10 AM 2/24/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Esseneite ITFA component 0
#%Empirical formula: CaFe3+AlSiO6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: Monoclinic  
#%Edge: K
#%Sample prep: powder on Kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:14 AM 2/25/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Esseneite ITFA component 1
#%Empirical formula: CaFe3+AlSiO6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: Monoclinic  
#%Edge: K
#%Sample prep: powder on Kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:14 AM 2/25/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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7.3995721E+3 1.0015456E+0
7.4045718E+3 1.0014303E+0
7.4095716E+3 9.9769022E-1




#%Name: Esseneite ITFA component 2
#%Empirical formula: CaFe3+AlSiO6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: Monoclinic  
#%Edge: K
#%Sample prep: powder on Kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:14 AM 2/25/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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7.4045718E+3 9.9652586E-1
7.4095716E+3 9.9760117E-1




#%Name: Esseneite ITFA component 3
#%Empirical formula: CaFe3+AlSiO6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: Monoclinic  
#%Edge: K
#%Sample prep: powder on Kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:14 AM 2/25/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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7.4095716E+3 9.9125863E-1




#%Name: Esseneite powder average
#%Empirical formula: CaFe3+AlSiO6 / Webmineral
#%Mineral group: clinopyroxenes, inosilicate
#%Xtal system: Monoclinic  
#%Edge: K
#%Sample prep: powder on Kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 4:14 AM 2/25/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Fe2O3/ Hematite
#%Empirical formula: Fe3+2O3 /webmineral
#%Mineral group: oxides
#%Xtal system: Hexagonal   
#%Edge: K
#%Sample prep: 
#%Beamline: ALS 10.3.2, HxV slits = 300x50 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Fe2O3 from Lytle filter
#%Temp: Room temp (28C)
#%Time&date: 1:20 AM 7/23/2004
#%Provider: Matthew A. Marcus, Yoo.
#%============================================================
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#%Name: Fe3C powder
#%Empirical formula: Fe3C
#%Mineral group: metal
#%Xtal system: orthorhombic   
#%Edge: K
#%Sample prep: powder on tape, 6 layers
#%Beamline: APS GSECARS 13BM, vert slits = 2mm (at 45m), Si(111) unfocussed, detuned 50%
#%Det:  I0=N2 15cm; I1=N2 15cm
#%Ref/notes:  http://cars9.uchicago.edu/~newville/ModelLib/, shifted by -300meV
#%Temp: Room temp
#%Time&date: 06:27 PM 03/16/2002 
#%Provider: Matt Newville.
#%============================================================
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#%Name: Fe3O4 (magnetite) powder
#%Empirical formula: Fe3+2Fe2+O4 /webmineral
#%Mineral group: oxides, spinel
#%Xtal system:  cubic  
#%Edge: K
#%Sample prep: powder on tape, 6 layers
#%Beamline: APS GSECARS 13BM, vert slits = 2mm (at 45m),Si(111) unfocussed, detuned 50%
#%Det:  I0=N2 15cm; I1=N2 15cm
#%Ref/notes:  http://cars9.uchicago.edu/~newville/ModelLib/, shifted by -300meV, overabsorption corrected
#%Temp: Room temp
#%Time&date: 07:08 PM 3/16/2002  
#%Provider: Matt Newville.
#%============================================================
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7.6548820E+3 9.9797534E-1
7.6594470E+3 9.9846732E-1
7.6640300E+3 9.9872052E-1




#%Name: Fe3Si
#%Empirical formula: Fe0+3Si 
#%Mineral group: silicide, metal
#%Xtal system: cubic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  none
#%Temp: Room temp (28C)
#%Time&date: 1:11 AM 6/21/2007
#%Provider: Matthew A. Marcus, Matthias Heuer, Tonio Buonassisi.
#%==============================================================
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#%Name: Fe Alginate complex 
#%Empirical formula: 
#%Mineral group:
#%Xtal system: 
#%Edge: K
#%Sample prep: solution in sealed capillary
#%Beamline: ALS 10.3.2, HxV slits = 300x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  none
#%Temp: Room temp (28C)
#%Time&date: 6:57 PM 8/19/2003
#%Provider: Clara S. Chan, Sirine Fakra
#%============================================================
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#%Name: FeCl3
#%Empirical formula: Fe3+Cl3
#%Mineral group:
#%Xtal system: hexagonal
#%Edge: K
#%Sample prep: solution in sealed capillary
#%Beamline: ALS 10.3.2, HxV slits = 300x30 um
#%Det:  I0=N2, transmission mode (ion chamber)
#%Ref/notes:  none
#%Temp: Room temp (28C)
#%Time&date: 1:03 PM 8/19/2003
#%Provider: Clara S. Chan, Sirine Fakra.
#%============================================================
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#%Name: Fe dextran complex
#%Empirical formula:
#%Mineral group:
#%Xtal system: 
#%Edge: K
#%Sample prep: solution in sealed capillary
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  glucan (polysaccharides)-Fe complex
#%Temp: Room temp (28C)
#%Time&date: 4:35 AM 8/20/2003
#%Provider: Clara S. Chan, Sirine Fakra.
#%============================================================
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7.6099195E+3 1.0048612E+0
7.6119205E+3 1.0067709E+0
7.6139216E+3 1.0052817E+0




#%Name: Fe metal foil
#%Empirical formula: Fe
#%Mineral group: metal
#%Xtal system: cubic
#%Edge: K
#%Sample prep: 5 microns thin foil
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, transmission mode (pin diode)
#%Ref/notes: EXAFS MATERIALS, CA- USA
#%Temp: Room temp (28C)
#%Time&date: 7:23 AM 2/9/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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7.4101060E+3 9.8219932E-1




#%Name: FeO powder
#%Empirical formula: Fe2+O
#%Mineral group: oxides
#%Xtal system:    
#%Edge: K
#%Sample prep: powder on tape
#%Beamline: APS GSECARS 13BM, vert slits = 2mm (at 45m),Si(111) unfocussed, detuned 50%
#%Det:  I0=N2 15cm; I1=N2 15cm
#%Ref/notes:  http://cars9.uchicago.edu/~newville/ModelLib/
#%Temp: Room temp
#%Time&date: 05:07 PM 03/16/2002
#%Provider: Matt Newville.
#%============================================================
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#%Name: Ferrihydrite 2 line
#%Empirical formula: Fe3+5HO8•4H2O approx./ wikipedia
#%Mineral group: oxyhydroxides
#%Xtal system: Hexagonal
#%Edge: K
#%Sample prep: powder on Kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 9:53 PM 3/14/2004 
#%Provider: Clara S. Chan, Sirine Fakra, Chris Kim.
#%============================================================
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#%Name: Ferrosilite ITFA component 0
#%Empirical formula: Fe2+MgSi2O6 / Webmineral
#%Mineral group: Orthopyroxenes, inosilicate
#%Xtal system: Orthorhombic 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state, 7 elements)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 2:04 AM 3/15/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Ferrosilite ITFA component 1
#%Empirical formula: Fe2+MgSi2O6 / Webmineral
#%Mineral group: Orthopyroxenes, inosilicate
#%Xtal system: Orthorhombic 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state, 7 elements)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 2:04 AM 3/15/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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7.3842007E+3 9.9849323E-1
7.3891999E+3 9.9443905E-1
7.3941992E+3 9.9867686E-1
7.3991984E+3 9.9132404E-1
7.4041976E+3 9.8755502E-1
7.4091968E+3 9.9341271E-1




#%Name: Ferrosilite ITFA component 2
#%Empirical formula: Fe2+MgSi2O6 / Webmineral
#%Mineral group: Orthopyroxenes, inosilicate
#%Xtal system: Orthorhombic 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state, 7 elements)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 2:04 AM 3/15/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Ferrosilite powder average
#%Empirical formula: Fe2+MgSi2O6 / Webmineral
#%Mineral group: Orthopyroxenes, inosilicate
#%Xtal system: Orthorhombic 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 200x30 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state, 7 elements)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 2:04 AM 3/15/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%============================================================
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#%Name: Ferrosmectite
#%Empirical formula: 
#%Mineral group: clays
#%Xtal system: 
#%Edge: K
#%Sample prep: 
#%Beamline: SSRL
#%Det: fluorescence mode
#%Ref/notes: iron-bearing montmorillonite sample from Joe Stucki at Univ. Illinois- USA. Raman confirmed.
#%Temp: Room temp
#%Time&date:
#%Provider: Thomas Borch, Colleen Hansel, Scott Fendorf
#%===================================================================
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#%Name: FeS synthetic
#%Empirical formula: FeS
#%Mineral group: sulfides
#%Xtal system: 
#%Edge: K
#%Sample prep:
#%Beamline: SSRL 
#%Det:  fluorescence mode
#%Ref/notes: STREM. Raman confirmed.
#%Temp: Room temp
#%Time&date: 
#%Provider: Thomas Borch, Colleen Hansel, Scott Fendorf.
#%===================================================================
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#%Name: FeSi2
#%Empirical formula: FeSi2
#%Mineral group: metal silicide
#%Xtal system: tetragonal / mincryst
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  none
#%Temp: Room temp (28C)
#%Time&date: 7:52 PM 6/20/2007
#%Provider: Tonio Buonassisi, Matthias Heuer, Matthew A. Marcus.
#%============================================================
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#%Name: FeSi 
#%Empirical formula: FeSi
#%Mineral group: metal silicide
#%Xtal system: 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  none
#%Temp: Room temp (28C)
#%Time&date: 11:44 PM 6/20/2007
#%Provider: Matthew A. Marcus, Tonio Buonassisi, Matthias Heuer.
#%===============================================================
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7.3932064E+3 1.0041307E+0
7.3981696E+3 1.0050811E+0
7.4031327E+3 1.0015517E+0




#%Name: Fo0 (fayalite), Fayalite-Forsterite Series
#%Empirical formula: Fe2SiO4
#%Mineral group: olivines
#%Xtal system: Orthorhombic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the National History Museum, London, UK. 
#%Temp: Room temp (28C)
#%Time&date: 3:29 AM 08/18/2006 
#%Provider: Anna Buttherworth, Sirine Fakra, Matthew A. Marcus.
#%==================================================
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7.4128702E+3 9.9945864E-1




#%Name: Fo40 forsterite, Fayalite-Forsterite Series
#%Empirical series formula: Fe2 2+ [SiO4]- Mg2[SiO4]
#%Mineral group: olivines
#%Xtal system: Orthorhombic
#%Edge: K 
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the National History Museum, London, UK.
#%Temp: Room temp (28C)
#%Time&date: 6:32 AM 02/19/2006
#%Provider: Anna Buttherworth, Sirine Fakra, Matthew A. Marcus.
#%==================================================
7.0103095E+3 -1.4574814E-3
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7.0253075E+3 1.4870106E-3
7.0303068E+3 5.1377107E-3
7.0353062E+3 2.5141227E-3
7.0403055E+3 -6.6885219E-4
7.0453049E+3 7.4546278E-3
7.0503042E+3 6.6393249E-3
7.0553035E+3 7.4257762E-3
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#%Name: Fo80 forsterite, Fayalite-Forsterite Series
#%Empirical series formula: Fe2 2+ [SiO4]- Mg2[SiO4]
#%Mineral group: olivines 
#%Xtal system: Orthorhombic
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  sample provided by the National History Museum, London, UK.
#%Temp: Room temp (28C)
#%Time&date: 8:11 AM 08/17/2006 
#%Provider: Anna Buttherworth, Sirine Fakra, Matthew A. Marcus.
#%==================================================
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7.9076669E+3 9.9538543E-1




#%Name: Gehlenite ITFA component 0
#%Empirical formula: Ca2Al2(Fe)SiO7
#%Mineral group: melilite
#%Xtal system: Tetragonal 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um 
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 1:36 PM 1/12/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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7.4097500E+3 9.8794396E-1




#%Name: Gehlenite ITFA component 1
#%Empirical formula: Ca2Al2(Fe)SiO7 
#%Mineral group: melilite
#%Xtal system: Tetragonal 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um 
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 1:36 PM 1/12/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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#%Name: Gehlenite ITFA component 2
#%Empirical formula: Ca2Al2(Fe)SiO7
#%Mineral group: melilite
#%Xtal system: Tetragonal 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um 
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 1:36 PM 1/12/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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7.4047500E+3 9.9243692E-1
7.4097500E+3 9.9433662E-1




#%Name: Gehlenite ITFA component 3
#%Empirical formula: Ca2Al2(Fe)SiO7
#%Mineral group: melilite
#%Xtal system: Tetragonal 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um 
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 1:36 PM 1/12/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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#%Name: Gehlenite powder average
#%Empirical formula: Ca2Al2(Fe)SiO7
#%Mineral group: melilite
#%Xtal system: Tetragonal 
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 100x20 um 
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  Mineralogical Research Company, San Jose, CA-USA. XRD confirmed.
#%Temp: Room temp (28C)
#%Time&date: 1:36 PM 1/12/2007
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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#%Name: Goethite
#%Empirical formula: alpha-Fe3+O(OH) 
#%Mineral group: oxyhydroxides
#%Xtal system: Orthorhombic  
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  XRD confirmed
#%Temp: Room temp (28C)
#%Time&date: 11:39 PM 03/17/2007 
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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7.6066913E+3 9.9830542E-1
7.6086905E+3 9.9959076E-1
7.6106898E+3 9.9908993E-1




#%Name: Goethite ITFA component 0
#%Empirical formula: alpha-Fe3+O(OH)
#%Mineral group: oxyhydroxides
#%Xtal system: Orthorhombic  
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  XRD confirmed
#%Temp: Room temp (28C)
#%Time&date: 11:39 PM 03/17/2007 
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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7.4061253E+3 9.9284029E-1




#%Name: Goethite ITFA component 1
#%Empirical formula: alpha-Fe3+O(OH)
#%Mineral group: oxyhydroxides
#%Xtal system: Orthorhombic  
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  XRD confirmed
#%Temp: Room temp (28C)
#%Time&date: 11:39 PM 03/17/2007 
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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7.0369865E+3 2.0603475E-3
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7.0469901E+3 2.0432490E-3
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#%Name: Goethite ITFA component 2
#%Empirical formula: alpha-Fe3+O(OH)
#%Mineral group: oxyhydroxides
#%Xtal system: Orthorhombic  
#%Edge: K
#%Sample prep: powder on kapton tape
#%Beamline: ALS 10.3.2, HxV slits = 50x20 um
#%Det:  I0=N2, Fluorescence mode (Ge solid state 7elts)
#%Ref/notes:  XRD confirmed
#%Temp: Room temp (28C)
#%Time&date: 11:39 PM 03/17/2007 
#%Provider: Sirine Fakra, Matthew A. Marcus.
#%==================================================
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