Figure 9
BOH3: Molecular shape dictates the arrangement of molecules along a twofold screw axis of length ∼18–19 Å. BOM1: slightly modified molecular arrangement leads to sandwich stacking. BOM3: another small variation gives rise to carbonyl dipolar interactions (dotted lines) and shortening of the unit-cell parameter to 14 Å (also observed in BCN3 which is isostructural with BOM3). H atoms have been omitted for clarity. |