Modified photoreactivity due to mixed crystal formation. II. Enhanced reactivity upon conformational mimicry and cavity enlargement

Vithana, C.; Uekusa, H.; Sekine, A.; Ohashi, Y.

doi:10.1107/S0108768102019663

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

IUCr IT WDC

home archive editors for authors for readers submit subscribe open access

view article

Figure 14
The first-order reaction rates observed for the 2ce3mpy, 2ce3epy, 2cp3mpy, Mix-I and Mix-II crystals. The increase in intensity of the IR peaks that are due to the CN stretching frequencies of the cyano groups is considered to give an estimate of the reaction rates. The values of C₀ and C_t indicate the concentration of the 1-cyanoethyl and/or 1-cyanopropyl complex(es) at the irradiation times 0 and t, respectively.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 58| Part 6| November 2002| Pages 986-997

doi:10.1107/S0108768102019663

Follow Acta Cryst. B

Search term		doi		Advanced search
Author		volume	page