Geometry at the aliphatic tertiary carbon atom: computational and experimental test of the Walsh rule

Böhm, S.; Exner, O.

doi:10.1107/S010876810302826X

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 4
The Walsh rule: plot of the averaged bond angles τ in the tert-butyl derivatives (2) versus the s-electron density at the CH₃ carbon atom; filled triangles denote substituents deviating for different possible reasons.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 60| Part 1| January 2004| Pages 103-107

doi:10.1107/S010876810302826X

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