Figure 17
TTF⋯CA – specific heat anomaly (i.e. background subtracted) for heating on the right and cooling on the left. The heating anomaly is an endotherm and the cooling anomaly an exotherm; this distinction would be shown by a DSC study which appears not to have been reported. T0 is shown by a vertical line at 81.20 K; the heating curve shows superheating of ∼ 2°, while the supercooling appears negligible. Adapted from Fig. 5(a) of Le Cointe (1994) and Fig. 5 of Buron-Le Cointe et al. (2003). |