Structure and phase transition of the Se-rich variety of antimonpearceite, [(Ag,Cu)6(Sb,As)2(S,Se)7][Ag9Cu(S,Se)2Se2]

Evain, M.; Bindi, L.; Menchetti, S.

doi:10.1107/S0108768106022798

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 4
Projection along the c axis of (a) the [Ag₉Cu(S,Se)₂Se₂]²⁺ B (B′) module layer of the lower-temperature Se-rich antimonpearceite structure and (b) the [Ag₉CuS₄]²⁺ B (B′) module layer of the 221-polybasite structure (Evain et al., 2006

). The sulfur environment around Cu is highlighted by thin S–S connecting lines.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 62| Part 5| September 2006| Pages 768-774

doi:10.1107/S0108768106022798

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