Commensurate (C6H14N2)2[Mo8O26]·4H2O and incommensurate (C6H14N2)2[Mo8O26]·4.66H2O: a structural versatility linked to solvent content

Evain, M.; Petricek, V.; Coué, V.; Dessapt, R.; Bujoli-Doeuff, M.; Jobic, S.

doi:10.1107/S0108768106025791

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 2
(a) View along the [01 $[\overline1]$ ] axis (b and c axes are therefore projected onto the view plane) of the structure of (I), showing the polyoxometalate anionic chains separated by the H₂DABCO²⁺ cations and the water molecules. (b) Projection along the [100] axis of the structure of (III) (Fang et al., 2004

), illustrating the two different orientations of the polyoxometalate chains and the parallel-like alignment of the H₂DABCO²⁺ cations with the chains.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 62| Part 5| September 2006| Pages 790-797

doi:10.1107/S0108768106025791

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