Solid-state compounds of stereoisomers: cis and trans isomers of 1,2-cyclohexanediol and 2,3-tetralindiol

Lloyd, M.A.; Patterson, G.E.; Simpson, G.H.; Duncan, L.L.; King, D.P.; Fu, Y.; Patrick, B.O.; Parkin, S.; Brock, C.P.

doi:10.1107/S0108768107010579

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 8
Possible hydrogen-bonding arrangements in the center of a molecular stack in the 1:1 compound of cis and trans 2,3-tetralindiol when both enantiomers of the latter can be present. Atoms C2, C3 and C4 are shown, as is one or both of the O atoms attached to C3. Gray lines indicated possible hydrogen bonds as identified in the fully disordered structure. (a) All possible positions of the hydroxyl O atoms attached to C3 are shown. (b) Hydrogen-bonding arrangement that would occur in the fully ordered compound between cis-2,3-tetralindiol and one of the pure enatiomers of trans-2,3-tetralindiol. (c) Hydrogen-bonding arrangement that could occur in a region in which R,R-2,3-tetralindiol molecules are replaced by the cis isomer, and the cis isomer is replaced by the S,S enantiomer.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 63| Part 3| May 2007| Pages 433-447

doi:10.1107/S0108768107010579

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