5d and 4f electron configuration of CeB6 at 340 and 535 K

Makita, R.; Tanaka, K.; Ōnuki, Y.

doi:10.1107/S0108768108026542

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 1
Schematic drawing of the energy levels of Ce and B (a) below room temperature and (b) at 535 K. The energy levels of Ce were estimated using the program HEX (Liberman et al., 1971

), those of B were calculated by Mann (1968

). The energy difference between 5d and 4f levels is approximately 56 times larger than that between 4f-Γ₈ and Γ₇ orbitals.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 64| Part 5| September 2008| Pages 534-549

doi:10.1107/S0108768108026542

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