Compounds with a `stuffed' anti-bixbyite-type structure, analysed in terms of the Zintl–Klemm and coordination-defect concepts

Vegas, A.; Martin, R.L.; Bevan, D.J.M.

doi:10.1107/S010876810803423X

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 3
(a) The AlN₂ substructure of the stuffed bixbyite Li₃AlN₂ formed by a three-dimensional network of AlN₄ tetrahedra which share all corners. (b) Detail of the four central tetrahedra to show their connectivity.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 65| Part 1| December 2009| Pages 11-21

doi:10.1107/S010876810803423X

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