[Ru(py)4Cl(NO)](PF6)2·0.5H2O: a model system for structural determination and ab initio calculations of photo-induced linkage NO isomers

Cormary, B.; Malfant, I.; Buron-Le Cointe, M.; Toupet, L.; Delley, B.; Schaniel, D.; Mockus, N.; Woike, T.; Fejfarová, K.; Petříček, V.; Dušek, M.

doi:10.1107/S0108768109027207

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 1
Ground state GS, isonitrosyl configuration SI, and side-on configuration SII of the [Fe(CN)₅NO]²⁻ ion after irradiation at T = 100 K with λ = 458 nm for SI and subsequent irradiation with 1064 nm for generation of SII.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 65| Part 5| September 2009| Pages 612-623

doi:10.1107/S0108768109027207

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