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Figure 3
Elemental anionic motif [Cd3Cl10]4− building an anionic substructure along with disordered isopropylammonium cations at T = 375 K. The dashed lines represent hydrogen bonds. All possible N—H⋯Cl contacts for IPA-A and IPA-B are marked with the appropriate H⋯Cl distances. The red bordered atoms represent symmetrically nonequivalent positions forming an asymmetric unit in the prototype Phase I; half-colored atoms possess 0.5 occupancy. H atoms bonded to disordered atoms are omitted for clarity. This figure is in color in the electronic version of this paper. |