Structural phase transitions in tetra(isopropyl­ammonium) decachlorotricadmate(II), [(CH3)2CHNH3]4Cd3Cl10, crystal with a two-dimensional cadmium(II) halide network

Gagor, A.; Waśkowska, A.; Czapla, Z.; Dacko, S.

doi:10.1107/S0108768110054583

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 5
Change in the positional disorder of isopropylammonium cations observed after transformation from Phase II (Pbca) to Phase III (P2₁2₁2₁) at 294 K. Possible H⋯Cl contacts are marked as dashed lines. The occupancy of the disordered positions in both phases for IPA-A and IPA-D is 0.5, whereas the occupancy of disordered IPA-B and IPA-C in Phase II is 0.45 (1) and 0.55 (1). H atoms bonded to disordered atoms are omitted for clarity.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 67| Part 2| February 2011| Pages 122-129

doi:10.1107/S0108768110054583

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