Effects of the [OC6F5] moiety upon structural geometry: crystal structures of half-sandwich tantalum(V) aryloxide complexes from reaction of Cp*Ta(NtBu)(CH2R)2 with pentafluorophenol

Cole, J.M.; Chan, M.C.W.; Gibson, V.C.; Howard, J.A.K.

doi:10.1107/S0108768111029259

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 8
A comparison of twist angles between the benzyl/pentafluorophenyl rings in (4) (left; twist angle is 42°) and (6) (right; twist angle is 77.1°).

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 67| Part 5| August 2011| Pages 416-424

doi:10.1107/S0108768111029259

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