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Figure 5
d(M—OH) determined by experiment for a variety of LDH phases plotted against the value calculated using ionic radii. The circles with full-line circumferences represent the data from structures that were determined using single crystals and the dotted-line circles are for structures determined using powder data. The lines are explained in the text. The data are from the following references: (1) For single crystals: Allmann (1968BB1, 1969BB2) (pyroaurite and `sjögrenite'); Arakcheeva et al. (1996BB4) (quintinite-2H-3c); Braithwaite et al. (1994BB14) (iowaite); Cooper & Hawthorne (1996BB27) (shigaite); Huminicki & Hawthorne (2003BB45) (nikischerite); Krivovichev et al. (2010aBB61) (quintinite-2H-3c); Krivovichev et al. (2010bBB62) (quintinite-1M); Merlino & Orlandi (2001BB73) (zaccagnaite); Pastor-Rodriguez & Taylor (1971BB84) (coalingite); Rius & Allmann (1984BB95) (wermlandite); Rius & Plana (1986BB96) (motukoreaite); Zhitova et al. (2010BB117) (quintinite-2H); (2) for powder where the data are used in the fit: Bellotto et al. (1996BB7) (Mg–Al); Constantino et al. (1998BB28) (Mg–Al); Ennadi et al. (2000BB33) (Zn–Al); Lombardo et al. (2005BB66) (Zn–Al–Cl); Lozano et al. (2012BB68) (Zn–Al, zaccagnaite-3R); Manohara & Vishnu Kamath (2010BB70) (Co–Ga, Mg–Ga); Manohara et al. (2011BB69) (Mg–Fe); Mills et al. (2011BB78) (Mg–Cr, barbertonite); Radha et al. (2007aBB90) (Zn–Al); Roussel et al. (2000BB98) (Zn–Cr); Witzke & Raade (2000BB113) (Zn–Al, zincwoodwardite); (3) powder data outliers: Lombardo et al. (2005BB66) (Zn–Al–CO3); Manohara & Vishnu Kamath (2010BB70) (Ni–Ga); Mills et al. (2011BB78) (Mg–Cr, stichtite); Radha et al. (2011BB92) (Zn–Al–SO3, Zn–Al–IO3); Radha et al. (2007bBB91) (Co–Al, Mg–Al).

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