Distortions of a flexible metal-organic framework from substituted pendant ligands

Munn, A.S.; Clarkson, G.J.; Walton, R.I.

doi:10.1107/S2052520613027224

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 3
Views of the structure of Co(BDC)(4-MeO-PNO): (a) along the a axis showing the filling of the diamond-shaped channels by the pendant ligand (only one orientation of the 4-MeO-PNO ligand is shown); (b) the two orientations of the 4-MeO-PNO ligand; (c) and (d) two views along the c axis showing the relative orientation of the pendant ligands and the bridging 1,4-benzenedicarboxylates, respectively. The inorganic chains in (c) and (d) are numbered according to the system in (a). H atoms are omitted for clarity.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 70| Part 1| December 2014| Pages 11-18

doi:10.1107/S2052520613027224

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