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Figure 4
Pressure dependence of (a) the Co—N bond lengths and (b) the amide C—N—C bond angles for α-Co(dca)2 (solid markers) and γ-Co(dca)2 (hollow markers). The different Co—N bond lengths are shown in red (axial, amide nitrogen) and black (equatorial, cyanide nitrogen) to highlight the elongation of the CoII octahedral in α-Co(dca)2. For γ-Co(dca)2 the average of the two unique Co—Neq bond lengths are shown. Vertical dashed lines indicate transition pressure. Error bars are within the size of the data points.

Journal logoSTRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS
ISSN: 2052-5206
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