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Figure 5
Representations of the crystal structures for α-Co(dca)2 at ∼ 0.4 GPa and γ-Co(dca)2 at ∼ 3.6 GPa. (a) Close-up view of the metal–ligand connectivity between four nearest-neighbour CoII centres with atoms from the asymmetric units labelled accordingly. (b) CoII octahedral packing diagrams as viewed in the (001) plane. C and N atoms are displayed as balls and sticks, respectively, for clarity. Symmetry codes: (i) -x, y, z; (ii) x, -y, -z; (iii) [{1\over 2}- x, -{1\over 2} + y, -{1\over 2} - z]; (iv) -x, -y, -z; (v) [{1\over 2} + x, {1\over 2} - y, {1\over 2} + z].

Journal logoSTRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS
ISSN: 2052-5206
Volume 71| Part 3| June 2015| Pages 252-257
https://doi.org/10.1107/S2052520615005867
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