Figure 10
Cu paddle wheel units in (a) STAM-1, (b) STAM-1MeOH and (c) STAM-1MeCN. Reduction in size of the `hydrophilic' channel resulting from ligand exchange in (d) STAM-1, (e) STAM-1MeOH, (f) STAM-1MeCN, viewed parallel to the c-axis. The part-occupied acetonitrile ligands are shown at full occupancy in (c), but the part-exchange is represented in (f) by showing coordination at only one of the potential three coordination sites. Image adapted from McKellar et al. (2014). |