Figure 15
Crystal structures of different magnesium formate frameworks, with green octahedra representing the coordination environments of Mg2+ ions: (a) dashkovaite (CSD reference: MGFORD04; Rossin et al., 2008); (b) magnesium formate MOF with the crs-topology, known as Basosiv M050 (CSD reference NAXVOY01; Rood et al., 2006); (c) anionic magnesium formate framework of pcu-topology (CSD reference: SIRBIG07; Shang et al., 2014) with ethylammonium guests omitted for clarity; and (d) anionic magnesium formate framework of acs-topology (CSD reference: NIWPIU; Mączka et al., 2014) with ammonium guests omitted for clarity. |