Rb2CaCu6(PO4)4O2, a novel oxophosphate with a shchurovskyite-type topology: synthesis, structure, magnetic properties and crystal chemistry of rubidium copper phosphates

Aksenov, S.M.; Borovikova, E.Y.; Mironov, V.S.; Yamnova, N.A.; Volkov, A.S.; Ksenofontov, D.A.; Gurbanova, O.A.; Dimitrova, O.V.; Deyneko, D.V.; Zvereva, E.A.; Maximova, O.V.; Krivovichev, S.V.; Burns, P.C.; Vasiliev, A.N.

doi:10.1107/S2052520619008527

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 3
Examples of the local structure of exchange-coupled pairs Cu–Cu in Rb₂CaCu₆(PO₄)₄O₂ employed for microscopic superexchange calculations. The basic CuO₄ squares of copper sites are shaded in light purple. Distances are given in Å.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 75| Part 5| October 2019| Pages 903-913

https://doi.org/10.1107/S2052520619008527

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