Figure 6
Principal layers observed in the SFCA-III modifications containing band-like units of octahedra (layer 1) as well as so-called winged-octahedra and vierer-single chains of tetrahedra (layer 2). Layers are presented in projections perpendicular to the sheets. (a) and (b): monoclinic form; (c) and (d): triclinic form. Dark-gray octahedra represent pure [CaO6]-units, whereas the octahedra about the remaining M-sites are given in light-gray. Tetrahedra are marked in blue. For sake of clarity, the contour of a single winged-octahedron is highlighted with bold lines. |