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Figure 12
Examples of a head-to-tail disorder of case I. (a), (b) p-Chloro­nitro­benzene, chemical formula and superposition of the two molecular orientations in the crystal structure; space group P21/a, Z = 2, molecular site symmetry [\bar 1] (Thomas et al., 2008BB38). (c), (d) 4-Fluoro­biphenyl, chemical formula and superposition of the two molecular orientations in the crystal structure; space group P 21/b 2/c 21/n, Z = 4. The long molecular axis coincides with the crystallographic twofold axis. The occupancies of the fluoro positions are 0.789 and 0.211 (Guzei et al., 2017BB13).

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