Study on the structural phase transitions in NaSICON-type compounds using Ag3Sc2(PO4)3 as a model system

Redhammer, G.J.; Tippelt, G.; Stahl, Q.; Benisek, A.; Rettenwander, D.

doi:10.1107/S2052520620014870

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 9
Part of the NaSICON structure of Ag₃Sc₂(PO₄)₃ at 298 K (C2/c), viewed down [010], showing a lantern unit and some neighbouring polyhedra for α-ASP. The atom nomenclature and equivalent atoms are as used in the text. [Symmetry codes: (xvii) x, y, z − 1; (xviii) −x + $[1 \over 2]$ , −y + $[1 \over 2]$ , −z; (xix) −x + 1, y, −z − $[1 \over 2]$ ; (xx) x + $[1 \over 2]$ , −y + $[1 \over 2]$ , z − $[1 \over 2]$ ; (xxi) −x + $[1 \over 2]$ , −y + $[1 \over 2]$ , −z − 1; (xxii) −x + 1, y, −z + $[1 \over 2]$ ; (xxiii) −x + 1, −y + 1, −z.]

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 77| Part 1| February 2021| Pages 10-22

https://doi.org/10.1107/S2052520620014870

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