Correlated disorder and crystal structure of β-VOSO4

Fuller, C.A.; Quintero-Castro, D.L.; Bosak, A.; Dyadkin, V.; Chernyshov, D.

doi:10.1107/S2052520622010083

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 1
The crystal structure of β-VOSO₄. (a) A single distorted VO₆ octahedron with short (vanadyl, S) and long (L) bonds. The octahedra are connected in chains, propagating along the a-axis with alternating bonding patterns. (b) Schematics of the bonding patterns for the two neighboring chains, gray crossed dots indicate inversion centers. (c) The VO₆ substructure, viewed down the a-axis, showing the alternating vanadyl bonding pattern.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 78| Part 6| December 2022| Pages 842-847

https://doi.org/10.1107/S2052520622010083

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