Structural insight into the cooperativity of spin crossover compounds

Shahed, H.; Sharma, N.; Angst, M.; Voigt, J.; Perßon, J.; Prakash, P.; Törnroos, K.W.; Chernyshov, D.; Gildenast, H.; Ohl, M.; Saffarini, G.; Grzechnik, A.; Friese, K.

doi:10.1107/S2052520623005814

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 11
Temperature dependence of U₂₂ (Å²) for the N atoms of (a) Bia-P_mono and (b) Bia-P_ortho. The gray dashed line represents the transition temperature. The schematic diagram insets in (a1), (a2) and (b2) show the molecular structure of the Fe(PM-Bia)₂(NCS)₂ and the corresponding ADPs of the N atoms bonded to Fe atom, respectively.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 79| Part 5| October 2023| Pages 354-367

https://doi.org/10.1107/S2052520623005814

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