Crystal structure solution and high-temperature thermal expansion in NaZr2(PO4)3-type materials

Hulbert, B.S.; Brodecki, J.E.; Kriven, W.M.

doi:10.1107/S2052520624001598

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 1
Crystal structure for CaZr₄P₆O₂₄ (CaZP) at 25°C in $[R{\bar 3}]$ (space group No. 148): (a) showing the corner-sharing nature of ZrO₆ octahedra and PO₄ tetrahedra seen in NZP-type materials, with alternate views (b) along the c axis and (c) along the b axis. SrZr₄P₆O₂₄ (SrZP) is isostructural, having the same space group, similar unit-cell lengths and atom positions.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 80| Part 2| April 2024| Pages 146-159

https://doi.org/10.1107/S2052520624001598

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