Solvatomorphism in a series of copper(II) complexes with the 5-phenyl­imidazole/perchlorate system as ligands

Loukopoulos, E.; Papatriantafyllopoulou, C.; Moushi, E.; Kitos, A.A.; Tasiopoulos, A.J.; Perlepes, S.P.; Nastopoulos, V.

doi:10.1107/S2052520624005948

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 6
(a) The dioxane molecules in compound 10·2(1,4-dioxane) filling the channels along the b axis in the middle of the unit cell. Only the H atoms involved in the interactions are shown. (b) The 2D layer formed by N1A—H1A⋯O4 interactions between the LH ligands and the perchlorate ions along b, and N1B—H1B⋯O5 interactions between the ligands and the 1,4-dioxane molecules in the [101] direction. Hanging contacts are drawn by red dotted lines. The dioxane molecules are highlighted.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 80| Part 4| August 2024| Pages 347-359

https://doi.org/10.1107/S2052520624005948

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