Structures of phospho­nitrides in light of the extended Zintl–Klemm concept

Vegas, A.; Osman, H.H.; Muñoz, A.; Blatov, V.A.; Manjón, F.J.

doi:10.1107/S2052520625004263

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 21
Mn-filled structure of the sod type formed by the P atoms in Mn₄P₆N₁₂S, showing the four-connectivity of P atoms (Ψ-Si) and the tetrahedral coordination of Ψ-SiO₄ units (highlighted on upper right). S atoms are located at the center of Mn₄ tetrahedra.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 81| Part 4| August 2025| Pages 378-394

https://doi.org/10.1107/S2052520625004263

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