Structures of phospho­nitrides in light of the extended Zintl–Klemm concept

Vegas, A.; Osman, H.H.; Muñoz, A.; Blatov, V.A.; Manjón, F.J.

doi:10.1107/S2052520625004263

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Figure 23
(a) The four-connected P skeleton in TiP₄N₄ in which P atoms center PN₄ tetrahedra, highlighted in the upper part. Ti atoms are located in the octagonal tunnels. (b) The structure of CrB₄ (crb). The charge transfer from Cr to B atoms makes B atoms adopt a Ψ-C skeleton.

STRUCTURAL SCIENCE
CRYSTAL ENGINEERING
MATERIALS

ISSN: 2052-5206

Volume 81| Part 4| August 2025| Pages 378-394

https://doi.org/10.1107/S2052520625004263

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