Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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CRYSTALLOGRAPHIC
COMMUNICATIONS

Volume 68| Part 10

ISSN: 2056-9890

October 2012 issue

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Cover illustration: 9,10-Dihydroanthracene-succinimides are target molecules for pharmaceutical and medical uses and their related pyrrolidines have also found applications as organocatalysts. In the title compound, C₂₅H₂₃N·CHCl₃, the N atom of the pyrrolidine heterocycle exhibits a pronounced pyramidalization [ [Sigma] (C-N-C) = 328.07°], indicating an accentuated N-donor character. In the crystal, this behaviour is evident by the C-HN hydrogen bond involving a solvent molecule and the N atom. In view of the presence of the chloroform solvent molecule is was possible to confirm crystallographically that the absolute configuration at the C-atom fused positions of the pyrrolidine group are S and R. See: Bratko, Ladeira, Saffon, Teuma & Gómez [Acta Cryst. (2012). E68, o2881].

inorganic compounds

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TiGeS₃

P. Kim and H. Yun

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Redetermination of junitoite, CaZn₂Si₂O₇·H₂O

H. Yang, N. G. Jenkins and R. T. Downs

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Robertsite, Ca₂Mn^III₃O₂(PO₄)₃·3H₂O

M. B. Andrade, S. M. Morrison, A. J. Di Domizio, M. N. Feinglos and R. T. Downs

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Caesium diuranium hexatelluride

A. Mesbah and J. A. Ibers

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Redetermination of Ba₂CdTe₃ from single-crystal X-ray data

M. Yang, S.-Q. Xia and X.-T. Tao

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Redetermination of clinobarylite, BaBe₂Si₂O₇

A. J. D. Domizio, R. T. Downs and H. Yang

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metal-organic compounds

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(18-Crown-6)potassium [(1,2,5,6-η)-cycloocta-1,5-diene][(1,2,3,4-η)-naphthalene]ferrate(−I)

W. W. Brennessel and J. E. Ellis

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(η⁶-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II)

A. Muller and W. L. Davis

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Tetrakis(dimethylammonium) trans-dichloridobis[5,5′-(pyrazine-2,3-diyl)bis(1H-tetrazol-1-ido-κN¹)]copper(II)

J.-H. Liao and P.-S. Shi

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Bis(methanol-κO)bis(1,2-diamino-2-hydroxyiminoethanone oximato-κ²N,N′)copper(II) bis(oxamide dioxime) methanol disolvate

D. Liu, R. Zhang, H. Hu, J. Qi and G. Yang

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Tris(2,2′-bipyridine-κ²N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ³O²,N,O⁶)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate

I. A. Golenya, A. N. Boyko, N. V. Kotova, M. Haukka and T. S. Iskenderov

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Diaquatris(nitrato-κ²O,O′){2,2′-[pyridine-2,6-diylbis(methyleneoxy)]dibenzaldehyde-κO¹}dysprosium(III)–2,2′-[pyridine-2,6-diylbis(methyleneoxy)]dibenzaldehyde (1/1)

S. L. Rodríguez de Luna, P. Elizondo, S. Bernès, M. Flores-Alamo and L. E. López

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Poly[μ₃-aqua-aqua(μ₃-3,5-dinitrobenzoato-κO¹:O³:O⁵)caesium]

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Guanidinium dioxidobis(picolinato-κ²N,O)(picolinato-κO)uranate(VI)

V. I. Mishkevich, M. S. Grigoriev, A. M. Fedosseev and P. Moisy

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catena-Poly[[dichloridomercury(II)]-μ-{N-[(E)-pyridin-2-ylmethylidene-κN]pyridin-3-amine-κ²N¹:N³}]

A. Mahmoudi, S. Dehghanpour, L. Najafi and M. Khalafbeigi

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Tetrabromidobis(dicyclohexylphosphane-κP)digallium(Ga—Ga)

D. H. Mayo, Y. Peng, P. Zavalij, K. H. Bowen and B. W. Eichhorn

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Diaquabis(1H-imidazole-4-carboxylato-κ²N³,O)cobalt(II)

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Bis[(1,1′-biphenyl-2,2′-diyl)di-tert-butylphosphonium] di-μ-chlorido-bis[dichloridopalladate(II)]

C. Arderne and C. W. Holzapfel

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(Naphthalene-2,3-diolato-κ²O,O′)[tris(pyridin-2-ylmethyl)amine-κ⁴N]cobalt(III) tetraphenylborate acetone monosolvate hemihydrate

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(Acetato-κO){bis[(2,4-dimethyl-1H-pyrazol-1-yl)methyl][(pyridin-2-yl)methyl]amine}cobalt(II) hexafluoridophosphate

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Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-ylmethylidene)ethanamine-κ³N,N′,N′′]manganese(II) monohydrate

D. Tinguiano, I. E. Thiam, M. Dieng, M. Gaye and P. Retailleau

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{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI)

H. Kargar and M. Kubicki

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Bromidobis[3-(1H-pyrazol-1-yl-κN²)propionamide-κO]copper(II) bromide methanol monosolvate

T. Wagner, C. G. Hrib, V. Lorenz, F. T. Edelmann and J. W. Gilje

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{4,4′-Dimethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate

F. Ganji, H. Kargar, R. Kia, V. Mirkhani and M. N. Tahir

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Trichlorido(dimethyl sulfoxide-κO)(di-2-pyridylamine-κ²N,N′)indium(III)

S. A. Shirvan, S. Haydari Dezfuli and E. Golabi

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(2.2.2-Cryptand)potassium tetrakis(η²-ethylene)cobaltate(−I)

W. W. Brennessel and J. E. Ellis

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(2,9-Dimethyl-1,10-phenanthroline-κ²N,N′)bis(thiocyanato-κS)mercury(II)

I. Warad, T. B. Hadda, B. Hammouti and S. F. Haddad

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(Acetato-κ²O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN¹)cobalt(II)

A. Tadjarodi, K. Bijanzad and B. Notash

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(2.2.2-Cryptand)potassium bis(cyanato-κN)(5,10,15,20-tetraphenylporphyrinato-κ⁴N)cobaltate(III) chlorobenzene hemisolvate

B. Belhaj Ali, M. S. Belkhiria, J.-C. Daran and H. Nasri

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Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ²O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate

N. Kim, Y. Yoon, H.-J. Lee and S. Yoon

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Tetrakis(μ₂-cyanido-κ²C:N)dicyanidotetrakis[tris(2-aminoethyl)amine-κ³N,N′,N′′,N′′′]tetracopper(II)iron(II) bis[pentacyanidonitrosoferrate(II)] hexahydrate

O. V. Kozachuk, J. A. Rusanova, O. V. Nesterova, R. Zubatyuk and O. V. Shishkin

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Poly[diammonium [(μ₄-butane-1,2,3,4-tetracarboxylato)zincate] tetrahydrate]

S. Jin, Y. Huang, S. Wei, Y. Zhou and Y. Zhou

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Poly[hexaaquabis(μ₄-pyrimidine-4,6-dicarboxylato)tetralithium]

W. Starosta and J. Leciejewicz

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Bis[4-amino-3,5-bis(pyridin-2-yl)-4H-1,2,4-triazole-κ²N¹,N⁵]diaquacobalt(II) bis(perchlorate)

M. Feng, Y.-F. Ji, S.-L. Liang and Z.-L. Liu

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3-(Ferrocen-1-ylcarbonyl)-1-methyl-4-(4-methylphenyl)spiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline]

B. Vijayakumar, D. Gavaskar, T. Srinivasan, R. Raghunathan and D. Velmurugan

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(μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.0^2,6.0^8,12]tetradec-13-ene-4,10-diido-κ²N:N′)bis[(2,2′-bipyridine-κ²N,N′)silver(I)] dihydrate

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Poly[(μ₄-biphenyl-2,4′-dicarboxylato-κ⁵O²:O^2′:O⁴:O⁴,O^4′)zinc]

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catena-Poly[[[iodidocopper(I)]-{μ-N-[(pyridin-2-yl-κN)methylidene]pyridin-3-amine-κ²N³:N¹}] acetonitrile hemisolvate]

A. Mahmoudi, S. Dehghanpour and M. Babakhodaverdi

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Trimethylammonium dichloridotriphenylstannate(IV)

T. Diop, L. Diop, J. P. Jasinski and A. C. Keeley

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Two coordination modes of Cu^II in a binuclear complex with N-(pyridin-2-ylcarbonyl)pyridine-2-carboxamidate ligands

J. J. Campos-Gaxiola, D. Morales-Morales, H. Höpfl, M. Parra-Hake and R. Reyes-Martínez

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{2,6-Bis[(2,6-diisopropylphosphanyl)oxy]-4-fluorophenyl-κ³P,C¹,P′}(1H-pyrazole-κN²)nickel(II) hexafluorophosphate

M.-L. Kwan, S. J. Conry, C. S. Carfagna, L. P. Press, O. V. Ozerov, N. W. Hoffman and R. E. Sykora

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Dibutylammonium bis(hydrogen methylphosphonato-κO)triphenylstannate(IV)

T. Diop, L. Diop, D. Fall and A. van der Lee

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Poly[diaqua[μ-1,4-bis(1H-imidazol-1-yl)benzene-κ²N³:N^3′](μ-fumarato-κ²O¹:O⁴)nickel(II)]

C.-X. Bian, X.-Q. Yao and Y.-M. Song

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Bis(1H-benzimidazole-2-carboxylato-κ²N³,O)bis(ethanol-κO)manganese(II)

J.-H. Nie, Y.-H. Lin and C.-T. Xu

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Poly[[μ₂-1,4-bis(imidazol-1-ylmethyl)benzene](μ₄-3,5,9,11-tetraoxo-4,10-diazatetracyclo[5.5.2.0^2,6.0^8,12]tetradec-13-ene-4,10-diido)disilver(I)]

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Poly[tetrakis(dimethylformamide)tris(μ₄-terephthalato)trimagnesium]

V. Koteswara Rao, M. Zeller and S. R. Lovelace-Cameron

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Octacarbonyldi-μ₂-hydrido-[μ₃-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium

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Di-μ-chlorido-bis{chlorido[2,3-dimethyl-N-(pyridin-2-ylmethylidene)aniline-κ²N,N′]mercury(II)}

S. J. Hoseyni, M. R. Talei Bavil Olyai and B. Notash

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Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate

Y.-H. Jiang, Q.-M. Qiu, R.-X. Jiang, X. Huang and Q.-H. Jin

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Tetrakis(μ-2-phenylquinoline-4-carboxylato-κ²O:O′)bis[(methanol-κO)copper(II)]

J. Guo and G. Yan

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Dioxido{4,4′,6,6′-tetrabromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}molybdenum(VI)

H. Kargar and M. N. Tahir

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catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ²N⁴:N^4′]] monohydrate]

Q.-X. Li, X.-J. Shi and L.-C. Chen

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Di-μ-chlorido-bis[(2-amino-4-methylpyridine-κN)chloridomercury(II)]

A. Tadjarodi, K. Bijanzad and B. Notash

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(1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II)

R. J. Kunnath, M. R. Prathapachandra Kurup and S. W. Ng

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Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium]

I. A. Golenya, Y. A. Izotova, N. I. Usenko, V. A. Kalibabchuk and N. V. Kotova

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Bis(μ-3-carboxy-2-hydroxypropane-1,2-dicarboxylato)bis(diaquazinc)–1,2-bis(pyridin-4-yl)ethene–water (1/1/2)

I. H. Hwang, P.-G. Kim, C. Kim and Y. Kim

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Poly[[diaqua(μ-4,4′-bipyridine N,N′-dioxide-κ²O:O′)(μ-terephthalato-κ²O¹:O⁴)cobalt(II)] 4,4′-bipyridine N,N′-dioxide monosolvate]

X. Ge and S.-Y. Song

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(Acetato-κ²O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ²P,C²]palladium(II)

C. Arderne and C. W. Holzapfel

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(2-Ethyl-2-oxazoline-κN)bis(N-ethyl-N-phenyldithiocarbamato-κ²S,S′)cadmium

D. C. Onwudiwe, C. A. Strydom and E. C. Hosten

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μ-Oxalato-κ⁴O¹,O²:O^1′,O^2′-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ²O,O′)lead(II)]

G.-H. Pan, J.-N. Tang, Z.-J. Huang, L. Li and C.-M. Zhang

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cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ²N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate

S. A. Shirvan, S. Haydari Dezfuli, E. Golabi and M. A. Gholamzadeh

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Tris(η⁵-cyclopentadienyl)-tris[η⁶-[9,10-dihydroanthracene-9,10-endo-3′,4′-(N-benzyl)pyrrolidine]]triruthenium(II) tris(hexafluorophosphate) acetone disolvate

I. Bratko, S. Mallet-Ladeira, N. Saffon, E. Teuma and M. Gómez

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Acta Cryst. (2012). E68, m1315
https://doi.org/10.1107/S1600536812040500