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The title compound, 8,8'-bis(dimethyl sulfido)-3,3'-ferra-commo-bis[3,1,2-ferradicarba-closo- dodecaborane(11)], has the expected overall geometry in which two {FeC2B9} icosahedra are linked via a common Fe atom; additionally, the whole cluster has crystallographically imposed C2 symmetry. The structure is compared with those of its geometric isomers and of some related compounds.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks bs8, global

hkl

Structure factor file (CIF format)
Contains datablock bs8

CCDC reference: 129761

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