metal-organic compounds
The title compound, [Ni(Cp)(PPh3)(CC—CC—H)] or [Ni(C4H)(C5H5)(C18H15P)], has metal–ligand dimensions of Ni—P 2.1410 (4), Ni—C 1.8383 (15) Å and P—Ni—C 93.47 (5)°, and principal alkyne dimensions of CC 1.212 (2) and 1.187 (3) Å, and CC—C 177.94 (19) and 179.5 (2)°. Intra- and intermolecular C—HCC interactions are present with the shortest CC distance being 3.198 Å.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129679